B(C6F5)3: a lewis acid that brings the light to the solid state
The straightforward coordination of the Lewis acid B(C6F5)3 to classical, non-emitting aldehydes results in solid-state photoluminescence. Variation of the electronic properties of the carbonyl moieties lead to the modulation of the solid-state emission colors, covering the entire visible spectrum w...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2016
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| In: |
Angewandte Chemie. International edition
Year: 2016, Jahrgang: 55, Heft: 3, Pages: 1196-1199 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201508461 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201508461 Resolving-System, Volltext: http://dx.doi.org/10.1002/anie.201508461 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201508461 |
| Verfasserangaben: | Max M. Hansmann, Alicia López-Andarias, Eva Rettenmeier, Carolina Egler-Lucas, Frank Rominger, A. Stephen K. Hashmi, and Carlos Romero-Nieto |
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| 245 | 1 | 0 | |a B(C6F5)3 |b a lewis acid that brings the light to the solid state |c Max M. Hansmann, Alicia López-Andarias, Eva Rettenmeier, Carolina Egler-Lucas, Frank Rominger, A. Stephen K. Hashmi, and Carlos Romero-Nieto |
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| 520 | |a The straightforward coordination of the Lewis acid B(C6F5)3 to classical, non-emitting aldehydes results in solid-state photoluminescence. Variation of the electronic properties of the carbonyl moieties lead to the modulation of the solid-state emission colors, covering the entire visible spectrum with quantum yields up to 0.64. Steady-state spectroscopy in combination with X-ray diffraction analysis and DFT calculations confirm that intermolecular interactions between the Lewis adducts are responsible for the observed luminescence. Alteration of the latter interactions induces, moreover, remarkable solid-state phenomena such as piezochromism. The versatility and simplicity of our approach facilitate the future development of solid-state emitting materials. | ||
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| 650 | 4 | |a boranes | |
| 650 | 4 | |a fluorescence | |
| 650 | 4 | |a piezochromism | |
| 650 | 4 | |a solid-state luminescence | |
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| 776 | 0 | 8 | |i Erscheint auch als |n Deutsche Ausgabe |a Hansmann, Max M., 1987 - |t Erzeugung von Festkörperlumineszenz durch Koordination der Lewis-Säure B(C6F5)3 an nicht-emittierende Aldehyde |d 2016 |w (DE-627)1524552011 |w (DE-576)454552017 |
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