Synthesis of indolo-quinonediimine derivatives by the thermolysis of 5-(1-benzotriazolyl)-substituted spiro[2H-benzimidazole-2,1‘-cyclohexane]

Nucleophilic introduction of the 1H-benzotriazole ring into spiro[2H-benzimidazole-2,1‘-cyclohexane] and spiro[2H-imidazo[4,5-b]pyridine-2,1‘-cyclohexane], followed by Graebe-Ullmann thermolysis, and also the reduction and formic acid cyclization of five spiro[cyclohexane-1,2‘-2‘H-imidazo[4,5-b]pyri...

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Bibliographic Details
Main Authors: Le, Huu Phuoc (Author) , Kelbig, Anna (Author) , Lindauer, Andreas (Author) , Neidlein, Richard (Author) , Suschitzky, Hans (Author)
Format: Article (Journal)
Language:English
Published: 2004
In: Journal of chemical research online. Synopses
Year: 2004, Issue: 7, Pages: 453-456
ISSN:1364-5560
DOI:10.3184/0308234042037347
Online Access:Verlag, kostenfrei, Volltext: http://dx.doi.org/10.3184/0308234042037347
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Author Notes:Huu Phuoc Le, Anna Kelbig, Andreas Lindauer, Richard Neidlein, and Hans Suschitzky
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Summary:Nucleophilic introduction of the 1H-benzotriazole ring into spiro[2H-benzimidazole-2,1‘-cyclohexane] and spiro[2H-imidazo[4,5-b]pyridine-2,1‘-cyclohexane], followed by Graebe-Ullmann thermolysis, and also the reduction and formic acid cyclization of five spiro[cyclohexane-1,2‘-2‘H-imidazo[4,5-b]pyridine] derivatives to give 5-substituted 1H-imidazo[4‘,5‘:5,6]pyrido[1,2-a]benzimidazoles, are described.
Item Description:Gesehen am 28.04.2017
Physical Description:Online Resource
ISSN:1364-5560
DOI:10.3184/0308234042037347