Photoredox-controlled mono- and di-multifluoroarylation of C(sp3)-H bonds with aryl fluorides
A controllable mono- and di-multifluoroarylation of acyclic and cyclic N-aryl amines with aryl fluorides by photocatalyzed dual C(sp3)−H/C(sp2)−F functionalization has been developed, providing new access to a wide array of valuable α-fluoroarylated amines. In addition, the one-pot consecutive heter...
Gespeichert in:
| Hauptverfasser: | , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
17 May 2017
|
| In: |
Angewandte Chemie. International edition
Year: 2017, Jahrgang: 56, Heft: 25, Pages: 7266-7270 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201700135 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/anie.201700135 Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/anie.201700135/abstract Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/anie.201700135/epdf 
|
| Verfasserangaben: | Jin Xie, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1562648888 | ||
| 003 | DE-627 | ||
| 005 | 20230427122037.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 170823s2017 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/anie.201700135 |2 doi | |
| 035 | |a (DE-627)1562648888 | ||
| 035 | |a (DE-576)492648883 | ||
| 035 | |a (DE-599)BSZ492648883 | ||
| 035 | |a (OCoLC)1340978380 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Xie, Jin |e VerfasserIn |0 (DE-588)107411695X |0 (DE-627)830254528 |0 (DE-576)437513521 |4 aut | |
| 245 | 1 | 0 | |a Photoredox-controlled mono- and di-multifluoroarylation of C(sp3)-H bonds with aryl fluorides |c Jin Xie, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi |
| 264 | 1 | |c 17 May 2017 | |
| 300 | |a 5 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Titel ist die Zahl 3 als Hochzahl dargestellt | ||
| 500 | |a Gesehen am 23.08.2017 | ||
| 520 | |a A controllable mono- and di-multifluoroarylation of acyclic and cyclic N-aryl amines with aryl fluorides by photocatalyzed dual C(sp3)−H/C(sp2)−F functionalization has been developed, providing new access to a wide array of valuable α-fluoroarylated amines. In addition, the one-pot consecutive hetero-di-multifluoroarylation of N-aryl pyrrolidines and N,N-dimethylanilines was achieved with high to excellent diastereoselectivity. This new defluorinative C(sp3)−C(sp2) coupling is distinguished by a broad scope, good regioselectivity, and mild conditions as well as gram-scale and late-stage applicability, and thus constitutes a significant advance in the arylation of unactivated C(sp3)−H bonds with aryl fluorides. | ||
| 650 | 4 | |a amines | |
| 650 | 4 | |a arylation | |
| 650 | 4 | |a iridium | |
| 650 | 4 | |a organofluorine compounds | |
| 650 | 4 | |a photoredox catalysis | |
| 700 | 1 | |a Rudolph, Matthias |d 1975- |e VerfasserIn |0 (DE-588)136790380 |0 (DE-627)587252405 |0 (DE-576)301277524 |4 aut | |
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
| 700 | 1 | |a Hashmi, A. Stephen K. |d 1963- |e VerfasserIn |0 (DE-588)101199576X |0 (DE-627)704823926 |0 (DE-576)169176665 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Angewandte Chemie. International edition |d Weinheim : Wiley-VCH, 1998 |g 56(2017), 25, Seite 7266-7270 |h Online-Ressource |w (DE-627)320497879 |w (DE-600)2011836-3 |w (DE-576)111552060 |x 1521-3773 |7 nnas |a Photoredox-controlled mono- and di-multifluoroarylation of C(sp3)-H bonds with aryl fluorides |
| 773 | 1 | 8 | |g volume:56 |g year:2017 |g number:25 |g pages:7266-7270 |g extent:5 |a Photoredox-controlled mono- and di-multifluoroarylation of C(sp3)-H bonds with aryl fluorides |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1002/anie.201700135 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u http://onlinelibrary.wiley.com/doi/10.1002/anie.201700135/abstract |x Verlag |3 Volltext |
| 856 | 4 | 0 | |u http://onlinelibrary.wiley.com/doi/10.1002/anie.201700135/epdf |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20170823 | ||
| 993 | |a Article | ||
| 994 | |a 2017 | ||
| 998 | |g 101199576X |a Hashmi, A. Stephen K. |m 101199576X:Hashmi, A. Stephen K. |d 120000 |d 120100 |e 120000PH101199576X |e 120100PH101199576X |k 0/120000/ |k 1/120000/120100/ |p 4 |y j | ||
| 998 | |g 1019978228 |a Rominger, Frank |m 1019978228:Rominger, Frank |d 120000 |d 120100 |e 120000PR1019978228 |e 120100PR1019978228 |k 0/120000/ |k 1/120000/120100/ |p 3 | ||
| 998 | |g 136790380 |a Rudolph, Matthias |m 136790380:Rudolph, Matthias |d 120000 |d 120100 |e 120000PR136790380 |e 120100PR136790380 |k 0/120000/ |k 1/120000/120100/ |p 2 | ||
| 998 | |g 107411695X |a Xie, Jin |m 107411695X:Xie, Jin |d 120000 |d 120100 |e 120000PX107411695X |e 120100PX107411695X |k 0/120000/ |k 1/120000/120100/ |p 1 |x j | ||
| 999 | |a KXP-PPN1562648888 |e 2978330910 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"language":["eng"],"title":[{"title":"Photoredox-controlled mono- and di-multifluoroarylation of C(sp3)-H bonds with aryl fluorides","title_sort":"Photoredox-controlled mono- and di-multifluoroarylation of C(sp3)-H bonds with aryl fluorides"}],"recId":"1562648888","name":{"displayForm":["Jin Xie, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi"]},"origin":[{"dateIssuedKey":"2017","dateIssuedDisp":"17 May 2017"}],"person":[{"role":"aut","family":"Xie","display":"Xie, Jin","given":"Jin"},{"role":"aut","family":"Rudolph","given":"Matthias","display":"Rudolph, Matthias"},{"display":"Rominger, Frank","given":"Frank","family":"Rominger","role":"aut"},{"role":"aut","family":"Hashmi","given":"A. Stephen K.","display":"Hashmi, A. Stephen K."}],"relHost":[{"recId":"320497879","disp":"Photoredox-controlled mono- and di-multifluoroarylation of C(sp3)-H bonds with aryl fluoridesAngewandte Chemie. International edition","titleAlt":[{"title":"Angewandte Chemie / International edition"}],"language":["eng"],"pubHistory":["37.1998 -"],"type":{"media":"Online-Ressource","bibl":"periodical"},"origin":[{"dateIssuedKey":"1998","publisherPlace":"Weinheim","publisher":"Wiley-VCH","dateIssuedDisp":"1998-"}],"corporate":[{"display":"Gesellschaft Deutscher Chemiker","role":"isb"}],"title":[{"title":"Angewandte Chemie","subtitle":"a journal of the Gesellschaft Deutscher Chemiker","title_sort":"Angewandte Chemie","partname":"International edition"}],"id":{"zdb":["2011836-3"],"issn":["1521-3773"],"doi":["10.1002/(ISSN)1521-3773"],"eki":["320497879"]},"part":{"pages":"7266-7270","year":"2017","text":"56(2017), 25, Seite 7266-7270","volume":"56","issue":"25","extent":"5"},"physDesc":[{"extent":"Online-Ressource"}],"note":["Gesehen am 20.12.2022","Fortsetzung der Druck-Ausgabe"]}],"note":["Im Titel ist die Zahl 3 als Hochzahl dargestellt","Gesehen am 23.08.2017"],"type":{"bibl":"article-journal","media":"Online-Ressource"},"id":{"doi":["10.1002/anie.201700135"],"eki":["1562648888"]},"physDesc":[{"extent":"5 S."}]} | ||
| SRT | |a XIEJINRUDOPHOTOREDOX1720 | ||