Gold-catalyzed formal cyclisation/dimerization of thiophene-tethered diynes
A new pathway in dual gold-catalyzed reaction of thiophene-tethered diynes has been identified. A series of fully conjugated alkynyl-substituted benzothiophenes and benzofurans was obtained by a formal cyclisation/dimerization sequence. All the products are fluorescent, owing to their extended conju...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
20 March 2017
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| In: |
Chemistry - a European journal
Year: 2017, Jahrgang: 23, Heft: 24, Pages: 5716-5721 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201700061 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/chem.201700061 Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/chem.201700061/epdf Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/chem.201700061/abstract |
| Verfasserangaben: | Svetlana Tšupova, Max M. Hansmann, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi |
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| 520 | |a A new pathway in dual gold-catalyzed reaction of thiophene-tethered diynes has been identified. A series of fully conjugated alkynyl-substituted benzothiophenes and benzofurans was obtained by a formal cyclisation/dimerization sequence. All the products are fluorescent, owing to their extended conjugation. The mechanistic studies have been carried out, suggesting that gold acetylides take part in this transformation. | ||
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