Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes: en route to tetrahydropyrimidines
Gold-catalyzed regioselective cyclocarboamination of ynamides with 1,3,5-triazinanes opens a facile and modular access to valuable 5-aminotetrahydropyrimidines in good to excellent yields. It constitutes an unprecedented yet challenging annulation of ynamides with unstrained saturated heterocycles....
Gespeichert in:
| Hauptverfasser: | , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
02 March 2017
|
| In: |
Chemical communications
Year: 2017, Jahrgang: 53, Heft: 31, Pages: 4304-4307 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C7CC00789B |
| Online-Zugang: | Verlag, Volltext: http://pubs.rsc.org/en/content/articlepdf/2017/cc/c7cc00789b Verlag, Volltext: http://dx.doi.org/10.1039/C7CC00789B Verlag, Volltext: http://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc00789b 
|
| Verfasserangaben: | Zhongyi Zeng, Hongming Jin, Xinlong Song, Qian Wang, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1562798081 | ||
| 003 | DE-627 | ||
| 005 | 20230427122042.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 170829s2017 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1039/C7CC00789B |2 doi | |
| 035 | |a (DE-627)1562798081 | ||
| 035 | |a (DE-576)492798087 | ||
| 035 | |a (DE-599)BSZ492798087 | ||
| 035 | |a (OCoLC)1340978738 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Zeng, Zhongyi |d 1989- |e VerfasserIn |0 (DE-588)1138948454 |0 (DE-627)896774902 |0 (DE-576)492785449 |4 aut | |
| 245 | 1 | 0 | |a Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes |b en route to tetrahydropyrimidines |c Zhongyi Zeng, Hongming Jin, Xinlong Song, Qian Wang, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi |
| 264 | 1 | |c 02 March 2017 | |
| 300 | |a 4 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 29.08.2017 | ||
| 520 | |a Gold-catalyzed regioselective cyclocarboamination of ynamides with 1,3,5-triazinanes opens a facile and modular access to valuable 5-aminotetrahydropyrimidines in good to excellent yields. It constitutes an unprecedented yet challenging annulation of ynamides with unstrained saturated heterocycles. This new protocol is distinguished by easy operation, readily available starting materials, stable four-atom building units, good functional-group compatibility and scaling-up potential. The preliminary mechanistic studies indicate that the present intermolecular cyclocarboamination arises from a pseudo-three-component [2+2+2] cycloaddition. | ||
| 700 | 1 | |a Jin, Hongming |e VerfasserIn |0 (DE-588)1081665785 |0 (DE-627)846460548 |0 (DE-576)454646860 |4 aut | |
| 700 | 1 | |a Song, Xinlong |e VerfasserIn |0 (DE-588)1138989703 |0 (DE-627)896775917 |0 (DE-576)492797900 |4 aut | |
| 700 | 1 | |a Wang, Qian |e VerfasserIn |0 (DE-588)1138948624 |0 (DE-627)896560708 |0 (DE-576)492785864 |4 aut | |
| 700 | 1 | |a Rudolph, Matthias |d 1975- |e VerfasserIn |0 (DE-588)136790380 |0 (DE-627)587252405 |0 (DE-576)301277524 |4 aut | |
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
| 700 | 1 | |a Hashmi, A. Stephen K. |d 1963- |e VerfasserIn |0 (DE-588)101199576X |0 (DE-627)704823926 |0 (DE-576)169176665 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemical communications |d Cambridge : Soc., 1965 |g 53(2017), 31, Seite 4304-4307 |h Online-Ressource |w (DE-627)268759081 |w (DE-600)1472881-3 |w (DE-576)077609867 |x 1364-548X |7 nnas |a Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes en route to tetrahydropyrimidines |
| 773 | 1 | 8 | |g volume:53 |g year:2017 |g number:31 |g pages:4304-4307 |g extent:4 |a Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes en route to tetrahydropyrimidines |
| 856 | 4 | 0 | |u http://pubs.rsc.org/en/content/articlepdf/2017/cc/c7cc00789b |x Verlag |3 Volltext |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1039/C7CC00789B |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u http://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc00789b |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20170829 | ||
| 993 | |a Article | ||
| 994 | |a 2017 | ||
| 998 | |g 101199576X |a Hashmi, A. Stephen K. |m 101199576X:Hashmi, A. Stephen K. |d 120000 |d 120100 |e 120000PH101199576X |e 120100PH101199576X |k 0/120000/ |k 1/120000/120100/ |p 7 |y j | ||
| 998 | |g 1019978228 |a Rominger, Frank |m 1019978228:Rominger, Frank |d 120000 |d 120100 |e 120000PR1019978228 |e 120100PR1019978228 |k 0/120000/ |k 1/120000/120100/ |p 6 | ||
| 998 | |g 136790380 |a Rudolph, Matthias |m 136790380:Rudolph, Matthias |d 120000 |d 120100 |e 120000PR136790380 |e 120100PR136790380 |k 0/120000/ |k 1/120000/120100/ |p 5 | ||
| 998 | |g 1138948624 |a Wang, Qian |m 1138948624:Wang, Qian |d 120000 |d 120100 |e 120000PW1138948624 |e 120100PW1138948624 |k 0/120000/ |k 1/120000/120100/ |p 4 | ||
| 998 | |g 1138989703 |a Song, Xinlong |m 1138989703:Song, Xinlong |d 120000 |d 120100 |e 120000PS1138989703 |e 120100PS1138989703 |k 0/120000/ |k 1/120000/120100/ |p 3 | ||
| 998 | |g 1081665785 |a Jin, Hongming |m 1081665785:Jin, Hongming |d 120000 |d 120100 |e 120000PJ1081665785 |e 120100PJ1081665785 |k 0/120000/ |k 1/120000/120100/ |p 2 | ||
| 998 | |g 1138948454 |a Zeng, Zhongyi |m 1138948454:Zeng, Zhongyi |d 120000 |d 120100 |e 120000PZ1138948454 |e 120100PZ1138948454 |k 0/120000/ |k 1/120000/120100/ |p 1 |x j | ||
| 999 | |a KXP-PPN1562798081 |e 2978660155 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"title":[{"title":"Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes","title_sort":"Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes","subtitle":"en route to tetrahydropyrimidines"}],"language":["eng"],"person":[{"display":"Zeng, Zhongyi","given":"Zhongyi","family":"Zeng","role":"aut"},{"family":"Jin","display":"Jin, Hongming","given":"Hongming","role":"aut"},{"family":"Song","display":"Song, Xinlong","given":"Xinlong","role":"aut"},{"given":"Qian","display":"Wang, Qian","family":"Wang","role":"aut"},{"role":"aut","display":"Rudolph, Matthias","given":"Matthias","family":"Rudolph"},{"given":"Frank","display":"Rominger, Frank","family":"Rominger","role":"aut"},{"given":"A. Stephen K.","display":"Hashmi, A. Stephen K.","family":"Hashmi","role":"aut"}],"name":{"displayForm":["Zhongyi Zeng, Hongming Jin, Xinlong Song, Qian Wang, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi"]},"origin":[{"dateIssuedDisp":"02 March 2017","dateIssuedKey":"2017"}],"recId":"1562798081","note":["Gesehen am 29.08.2017"],"relHost":[{"pubHistory":["1996 -"],"type":{"media":"Online-Ressource","bibl":"periodical"},"disp":"Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes en route to tetrahydropyrimidinesChemical communications","recId":"268759081","titleAlt":[{"title":"ChemComm online"},{"title":"Chemical communications online"},{"title":"Chemical communications (1996)"}],"language":["eng"],"id":{"zdb":["1472881-3"],"issn":["1364-548X"],"eki":["268759081"]},"part":{"pages":"4304-4307","year":"2017","volume":"53","text":"53(2017), 31, Seite 4304-4307","issue":"31","extent":"4"},"physDesc":[{"extent":"Online-Ressource"}],"note":["Gesehen am 27.01.26"],"origin":[{"publisherPlace":"Cambridge","dateIssuedKey":"1996","dateIssuedDisp":"1996-","publisher":"Soc."}],"name":{"displayForm":["The Royal Society of Chemistry"]},"corporate":[{"role":"isb","display":"Royal Society of Chemistry"}],"title":[{"title_sort":"Chemical communications","subtitle":"ChemComm","title":"Chemical communications"}]}],"physDesc":[{"extent":"4 S."}],"id":{"eki":["1562798081"],"doi":["10.1039/C7CC00789B"]},"type":{"media":"Online-Ressource","bibl":"article-journal"}} | ||
| SRT | |a ZENGZHONGYGOLDCATALY0220 | ||