Silver-catalyzed decarboxylative alkynylation of α,α-difluoroarylacetic acids with ethynylbenziodoxolone reagents

A decarboxylating alkynylation of α,α-difluoroarylacetic acids with ethynylbenziodoxolone reagents is reported. AgNO3 serves as the catalyst and K2S2O8 as the oxidant. A series of functional groups were tolerated, and moderate to good yields were obtained.

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Bibliographische Detailangaben
Hauptverfasser: Chen, Fei (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: June 8, 2016
In: Organic letters
Year: 2016, Jahrgang: 18, Heft: 12, Pages: 2880-2882
ISSN:1523-7052
DOI:10.1021/acs.orglett.6b01188
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1021/acs.orglett.6b01188
Volltext
Verfasserangaben:Fei Chen, A. Stephen K. Hashmi

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