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Synthesis of different classes of six-membered gold(I) NHC complexes by the isonitrile route

Different types of six-membered N-heterocyclic gold carbene complexes were prepared by using gold(I) isonitrile complexes as precursors in combination with suitably functionalized amines. The simple procedures provide an easy access to not only unsymmetrically substituted saturated carbene complexes...

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Main Authors: Wurm, Thomas (Author) , Mulks, Florian (Author) , Böhling, Constantin R. N. (Author) , Riedel, Dominic (Author) , Zargaran, Poorya (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: April 11, 2016
In: Organometallics
Year: 2016, Volume: 35, Issue: 8, Pages: 1070-1078
ISSN:1520-6041
DOI:10.1021/acs.organomet.6b00023
Online Access:Verlag, Volltext: http://dx.doi.org/10.1021/acs.organomet.6b00023
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Author Notes:Thomas Wurm, Florian Mulks, Constantin R.N. Böhling, Dominic Riedel, Poorya Zargaran, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi
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Summary:Different types of six-membered N-heterocyclic gold carbene complexes were prepared by using gold(I) isonitrile complexes as precursors in combination with suitably functionalized amines. The simple procedures provide an easy access to not only unsymmetrically substituted saturated carbene complexes but rarely reported types of carbene complexes such as six-membered N-heterocyclic oxo-carbene complexes, and six-membered partly unsaturated ligands can be obtained following the strategy.
Item Description:Gesehen am 29.09.2016
Physical Description:Online Resource
ISSN:1520-6041
DOI:10.1021/acs.organomet.6b00023

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