Buchumschlag

Facile synthesis of functionalized carbene metal complexes from coordinated isonitriles

The scope and limitations of the isonitrile-based NHC template synthesis were investigated with a series of precursors containing a nucleophilic amine in combination with tethered electrophiles. In the case of alkynes and phosphonic esters as electrophiles no ring closure was observed and new functi...

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Bibliographische Detailangaben
Hauptverfasser: Lothschütz, Christian (VerfasserIn) , Wurm, Thomas (VerfasserIn) , Zeiler, Anna (VerfasserIn) , Rudolph, Matthias (VerfasserIn) , Rominger, Frank (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 4 February 2016
In: Chemistry
Year: 2016, Jahrgang: 11, Heft: 3, Pages: 342-346
ISSN:1861-471X
DOI:10.1002/asia.201500353
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1002/asia.201500353
Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/asia.201500353/abstract
Volltext
Verfasserangaben:Christian Lothschütz, Thomas Wurm, Anna Zeiler, Alexander Freiherr v. Falkenhausen, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi
Beschreibung
Zusammenfassung:The scope and limitations of the isonitrile-based NHC template synthesis were investigated with a series of precursors containing a nucleophilic amine in combination with tethered electrophiles. In the case of alkynes and phosphonic esters as electrophiles no ring closure was observed and new functionalized NAC gold complexes were obtained. By the use of unsaturated esters and phosphonic esters as Michael acceptors in the amine precursors, ester-modified gold and palladium NHC complexes were accessible in high efficiency.
Beschreibung:Gesehen am 02.10.2017
Jahr auch angegeben als: First published 3 July 2015
Beschreibung:Online Resource
ISSN:1861-471X
DOI:10.1002/asia.201500353

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