Probing electronic correlations in actinide materials using multipolar transitions

We report nonresonant inelastic x-ray scattering from the semicore 5d levels of several actinide compounds. Dipole-forbidden, high-multipole features form a rich bound-state spectrum dependent on valence electron configuration and spin-orbit and Coulomb interactions. Cross-material comparisons, toge...

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Hauptverfasser: Bradley, J. A. (VerfasserIn) , Haverkort, Maurits W. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 28 May 2010
In: Physical review. B, Condensed matter and materials physics
Year: 2010, Jahrgang: 81, Heft: 19, Pages: 193104
ISSN:1550-235X
DOI:10.1103/PhysRevB.81.193104
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1103/PhysRevB.81.193104
Verlag, Volltext: https://link.aps.org/doi/10.1103/PhysRevB.81.193104
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Verfasserangaben:J.A. Bradley, S. Sen Gupta, G.T. Seidler, K.T. Moore, M.W. Haverkort, G.A. Sawatzky, S.D. Conradson, D.L. Clark, S.A. Kozimor, and K.S. Boland

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520 |a We report nonresonant inelastic x-ray scattering from the semicore 5d levels of several actinide compounds. Dipole-forbidden, high-multipole features form a rich bound-state spectrum dependent on valence electron configuration and spin-orbit and Coulomb interactions. Cross-material comparisons, together with the anomalously high Coulomb screening required for agreement between atomic-multiplet theory and experiment, demonstrate sensitivity to the neighboring electronic environment, such as is needed to address longstanding questions of electronic localization and bonding in 5f compounds. 
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