Crystal-field level inversion in lightly Mn-doped Sr 3 Ru 2 O 7
Sr3(Ru1−xMnx)2O7, in which 4d-Ru is substituted by the more localized 3d-Mn, is studied by x-ray dichroism and spin-resolved density functional theory. We find that Mn impurities do not exhibit the same 4+ valence of Ru, but act as 3+ acceptors; the extra eg electron occupies the in-plane 3dx2−y2 or...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
3 July 2008
|
| In: |
Physical review letters
Year: 2008, Jahrgang: 101, Heft: 1 |
| ISSN: | 1079-7114 |
| DOI: | 10.1103/PhysRevLett.101.016404 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1103/PhysRevLett.101.016404 Verlag, Volltext: https://link.aps.org/doi/10.1103/PhysRevLett.101.016404 
|
| Verfasserangaben: | M.A. Hossain, Z. Hu, M.W. Haverkort, T. Burnus, C.F. Chang, S. Klein, J.D. Denlinger, H.-J. Lin, C.T. Chen, R. Mathieu, Y. Kaneko, Y. Tokura, S. Satow, Y. Yoshida, H. Takagi, A. Tanaka, I.S. Elfimov, G.A. Sawatzky, L.H. Tjeng, and A. Damascelli |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1565099230 | ||
| 003 | DE-627 | ||
| 005 | 20220814015012.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 171107s2008 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1103/PhysRevLett.101.016404 |2 doi | |
| 035 | |a (DE-627)1565099230 | ||
| 035 | |a (DE-576)495099236 | ||
| 035 | |a (DE-599)BSZ495099236 | ||
| 035 | |a (OCoLC)1340981715 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 29 |2 sdnb | ||
| 100 | 1 | |a Hossain, Suman |e VerfasserIn |0 (DE-588)1141199009 |0 (DE-627)898953022 |0 (DE-576)494253053 |4 aut | |
| 245 | 1 | 0 | |a Crystal-field level inversion in lightly Mn-doped Sr 3 Ru 2 O 7 |c M.A. Hossain, Z. Hu, M.W. Haverkort, T. Burnus, C.F. Chang, S. Klein, J.D. Denlinger, H.-J. Lin, C.T. Chen, R. Mathieu, Y. Kaneko, Y. Tokura, S. Satow, Y. Yoshida, H. Takagi, A. Tanaka, I.S. Elfimov, G.A. Sawatzky, L.H. Tjeng, and A. Damascelli |
| 264 | 1 | |c 3 July 2008 | |
| 300 | |a 4 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Die Ziffern "3", "2" und "7" im Titel sind tiefgestellt | ||
| 500 | |a Gesehen am 07.11.2017 | ||
| 520 | |a Sr3(Ru1−xMnx)2O7, in which 4d-Ru is substituted by the more localized 3d-Mn, is studied by x-ray dichroism and spin-resolved density functional theory. We find that Mn impurities do not exhibit the same 4+ valence of Ru, but act as 3+ acceptors; the extra eg electron occupies the in-plane 3dx2−y2 orbital instead of the expected out-of-plane 3d3z2−r2. We propose that the 3d−4d interplay, via the ligand oxygen orbitals, is responsible for this crystal-field level inversion and the material’s transition to an antiferromagnetic, possibly orbitally ordered, low-temperature state. | ||
| 700 | 1 | |a Haverkort, Maurits W. |d 1976- |e VerfasserIn |0 (DE-588)130132047 |0 (DE-627)491717946 |0 (DE-576)257824006 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Physical review letters |d College Park, Md. : APS, 1958 |g 101(2008,1) Artikel-Nummer 016404, 4 Seiten |h Online-Ressource |w (DE-627)268756899 |w (DE-600)1472655-5 |w (DE-576)077609441 |x 1079-7114 |7 nnas |a Crystal-field level inversion in lightly Mn-doped Sr 3 Ru 2 O 7 |
| 773 | 1 | 8 | |g volume:101 |g year:2008 |g number:1 |g extent:4 |a Crystal-field level inversion in lightly Mn-doped Sr 3 Ru 2 O 7 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1103/PhysRevLett.101.016404 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://link.aps.org/doi/10.1103/PhysRevLett.101.016404 |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20171107 | ||
| 993 | |a Article | ||
| 994 | |a 2008 | ||
| 998 | |g 130132047 |a Haverkort, Maurits W. |m 130132047:Haverkort, Maurits W. |p 3 | ||
| 999 | |a KXP-PPN1565099230 |e 2986709923 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"recId":"1565099230","note":["Die Ziffern \"3\", \"2\" und \"7\" im Titel sind tiefgestellt","Gesehen am 07.11.2017"],"name":{"displayForm":["M.A. Hossain, Z. Hu, M.W. Haverkort, T. Burnus, C.F. Chang, S. Klein, J.D. Denlinger, H.-J. Lin, C.T. Chen, R. Mathieu, Y. Kaneko, Y. Tokura, S. Satow, Y. Yoshida, H. Takagi, A. Tanaka, I.S. Elfimov, G.A. Sawatzky, L.H. Tjeng, and A. Damascelli"]},"relHost":[{"language":["eng"],"type":{"bibl":"periodical","media":"Online-Ressource"},"corporate":[{"display":"American Physical Society","role":"isb"}],"id":{"eki":["268756899"],"zdb":["1472655-5"],"issn":["1079-7114"]},"origin":[{"dateIssuedDisp":"1958-","publisherPlace":"College Park, Md.","dateIssuedKey":"1958","publisher":"APS"}],"part":{"text":"101(2008,1) Artikel-Nummer 016404, 4 Seiten","issue":"1","volume":"101","extent":"4","year":"2008"},"title":[{"title_sort":"Physical review letters","title":"Physical review letters"}],"titleAlt":[{"title":"Physical review letters online"},{"title":"Physical review L"}],"physDesc":[{"extent":"Online-Ressource"}],"disp":"Crystal-field level inversion in lightly Mn-doped Sr 3 Ru 2 O 7Physical review letters","note":["Gesehen am 23.08.2019"],"pubHistory":["1.1958 -"],"recId":"268756899","name":{"displayForm":["publ. by the American Physical Society"]}}],"person":[{"given":"Suman","display":"Hossain, Suman","family":"Hossain","role":"aut"},{"role":"aut","display":"Haverkort, Maurits W.","family":"Haverkort","given":"Maurits W."}],"title":[{"title_sort":"Crystal-field level inversion in lightly Mn-doped Sr 3 Ru 2 O 7","title":"Crystal-field level inversion in lightly Mn-doped Sr 3 Ru 2 O 7"}],"physDesc":[{"extent":"4 S."}],"origin":[{"dateIssuedDisp":"3 July 2008","dateIssuedKey":"2008"}],"id":{"eki":["1565099230"],"doi":["10.1103/PhysRevLett.101.016404"]},"language":["eng"],"type":{"media":"Online-Ressource","bibl":"article-journal"}} | ||
| SRT | |a HOSSAINSUMCRYSTALFIE3200 | ||