Evidence for a temperature-induced spin-state transition of Co3+ in La2-xSrxCoO4

We study the magnetic susceptibility of mixed-valent La2-xSrxCoO4 single crystals in the doping range of 0.5<= x <= 0.8 for temperatures up to 1000 K. The magnetism below room temperature is described by paramagnetic Co2+ in the high-spin state and by Co3+ in the non-magnetic low-spin state. A...

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Bibliographic Details
Main Authors: Hollmann, Nils (Author) , Haverkort, Maurits W. (Author)
Format: Article (Journal) Chapter/Article
Language:English
Published: 2011
In: Arxiv

Online Access:Verlag, kostenfrei, Volltext: http://arxiv.org/abs/1204.0730
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Author Notes:N. Hollmann, M.W. Haverkort, M. Benomar, M. Cwik, M. Braden, and T. Lorenz
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