Crystal-field level inversion in lightly Mn-doped Sr3Ru2O7
Sr3(Ru1-xMnx)2O7, in which 4d-Ru is substituted by the more localized 3d-Mn, is studied by x-ray dichroism and spin-resolved density functional theory. We find that Mn impurities do not exhibit the same 4+ valence of Ru, but act as 3+ acceptors; the extra eg electron occupies the in-plane 3dx2-y2 or...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Dokumenttyp: | Article (Journal) Kapitel/Artikel |
| Sprache: | Englisch |
| Veröffentlicht: |
2008
|
| In: |
Arxiv
|
| Online-Zugang: | Verlag, kostenfrei, Volltext: http://arxiv.org/abs/0801.2995
|
| Verfasserangaben: | M.A. Hossain, Z. Hu, M.W. Haverkort, T. Burnus, C.F. Chang, S. Klein, J.D. Denlinger, H.-J. Lin, C.T. Chen, R. Mathieu, Y. Kaneko, Y. Tokura, S. Satow, Y. Yoshida, H. Takagi, A. Tanaka, I.S. Elfimov, G.A. Sawatzky, L.H. Tjeng, and A. Damascelli |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1565727630 | ||
| 003 | DE-627 | ||
| 005 | 20220814031922.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 171127s2008 xx |||||o 00| ||eng c | ||
| 035 | |a (DE-627)1565727630 | ||
| 035 | |a (DE-576)495727636 | ||
| 035 | |a (DE-599)BSZ495727636 | ||
| 035 | |a (OCoLC)1340982662 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 29 |2 sdnb | ||
| 100 | 1 | |a Hossain, Suman |e VerfasserIn |0 (DE-588)1141199009 |0 (DE-627)898953022 |0 (DE-576)494253053 |4 aut | |
| 245 | 1 | 0 | |a Crystal-field level inversion in lightly Mn-doped Sr3Ru2O7 |c M.A. Hossain, Z. Hu, M.W. Haverkort, T. Burnus, C.F. Chang, S. Klein, J.D. Denlinger, H.-J. Lin, C.T. Chen, R. Mathieu, Y. Kaneko, Y. Tokura, S. Satow, Y. Yoshida, H. Takagi, A. Tanaka, I.S. Elfimov, G.A. Sawatzky, L.H. Tjeng, and A. Damascelli |
| 264 | 1 | |c 2008 | |
| 300 | |a 4 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Die Ziffern "3", "2" und "7" im Titel sind tiefgestellt | ||
| 500 | |a Gesehen am 27.11.2017 | ||
| 520 | |a Sr3(Ru1-xMnx)2O7, in which 4d-Ru is substituted by the more localized 3d-Mn, is studied by x-ray dichroism and spin-resolved density functional theory. We find that Mn impurities do not exhibit the same 4+ valence of Ru, but act as 3+ acceptors; the extra eg electron occupies the in-plane 3dx2-y2 orbital instead of the expected out-of-plane 3d3z2-r2. We propose that the 3d-4d interplay, via the ligand oxygen orbitals, is responsible for this crystal-field level inversion and the material's transition to an antiferromagnetic, possibly orbitally-ordered, low-temperature state. | ||
| 650 | 4 | |a Condensed Matter - Strongly Correlated Electrons | |
| 700 | 1 | |a Haverkort, Maurits W. |d 1976- |e VerfasserIn |0 (DE-588)130132047 |0 (DE-627)491717946 |0 (DE-576)257824006 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Arxiv |d Ithaca, NY : Cornell University, 1991 |g (2008) Artikel-Nummer 0801.2995, 4 Seiten |h Online-Ressource |w (DE-627)509006531 |w (DE-600)2225896-6 |w (DE-576)28130436X |7 nnas |a Crystal-field level inversion in lightly Mn-doped Sr3Ru2O7 |
| 773 | 1 | 8 | |g year:2008 |g extent:4 |a Crystal-field level inversion in lightly Mn-doped Sr3Ru2O7 |
| 856 | 4 | 0 | |u http://arxiv.org/abs/0801.2995 |x Verlag |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20171127 | ||
| 993 | |a Article | ||
| 998 | |g 130132047 |a Haverkort, Maurits W. |m 130132047:Haverkort, Maurits W. |p 3 | ||
| 999 | |a KXP-PPN1565727630 |e 2988273464 | ||
| BIB | |a Y | ||
| JSO | |a {"name":{"displayForm":["M.A. Hossain, Z. Hu, M.W. Haverkort, T. Burnus, C.F. Chang, S. Klein, J.D. Denlinger, H.-J. Lin, C.T. Chen, R. Mathieu, Y. Kaneko, Y. Tokura, S. Satow, Y. Yoshida, H. Takagi, A. Tanaka, I.S. Elfimov, G.A. Sawatzky, L.H. Tjeng, and A. Damascelli"]},"note":["Die Ziffern \"3\", \"2\" und \"7\" im Titel sind tiefgestellt","Gesehen am 27.11.2017"],"recId":"1565727630","person":[{"display":"Hossain, Suman","family":"Hossain","given":"Suman","role":"aut"},{"role":"aut","display":"Haverkort, Maurits W.","family":"Haverkort","given":"Maurits W."}],"physDesc":[{"extent":"4 S."}],"title":[{"title_sort":"Crystal-field level inversion in lightly Mn-doped Sr3Ru2O7","title":"Crystal-field level inversion in lightly Mn-doped Sr3Ru2O7"}],"relHost":[{"origin":[{"dateIssuedDisp":"1991-","publisherPlace":"Ithaca, NY ; [Erscheinungsort nicht ermittelbar]","publisher":"Cornell University ; Arxiv.org","dateIssuedKey":"1991"}],"language":["eng"],"id":{"zdb":["2225896-6"],"eki":["509006531"]},"type":{"bibl":"edited-book","media":"Online-Ressource"},"physDesc":[{"extent":"Online-Ressource"}],"title":[{"title":"Arxiv","title_sort":"Arxiv"}],"titleAlt":[{"title":"Arxiv.org"},{"title":"Arxiv.org e-print archive"},{"title":"Arxiv e-print archive"},{"title":"De.arxiv.org"}],"part":{"extent":"4","year":"2008","text":"(2008) Artikel-Nummer 0801.2995, 4 Seiten"},"disp":"Crystal-field level inversion in lightly Mn-doped Sr3Ru2O7Arxiv","note":["Gesehen am 28.05.2024"],"pubHistory":["1991 -"],"recId":"509006531"}],"origin":[{"dateIssuedDisp":"2008","dateIssuedKey":"2008"}],"id":{"eki":["1565727630"]},"type":{"bibl":"chapter","media":"Online-Ressource"},"language":["eng"]} | ||
| SRT | |a HOSSAINSUMCRYSTALFIE2008 | ||