A different look at the spin state of Co3+ ions in CoO5 pyramidal coordination
Using soft-x-ray absorption spectroscopy at the Co-$L_{2,3}$ and O-$K$ edges, we demonstrate that the Co$^{3+}$ ions with the CoO$_{5}$ pyramidal coordination in the layered Sr$_2$CoO$_3$Cl compound are unambiguously in the high spin state. Our result questions the reliability of the spin state assi...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Dokumenttyp: | Article (Journal) Kapitel/Artikel |
| Sprache: | Englisch |
| Veröffentlicht: |
2003
|
| In: |
Arxiv
|
| Online-Zugang: | Verlag, kostenfrei, Volltext: http://arxiv.org/abs/cond-mat/0310138
|
| Verfasserangaben: | Z. Hu, Hua Wu, M.W. Haverkort, H.H. Hsieh, H.-J. Lin, T. Lorenz, J. Baier, A. Reichl, I. Bonn, C. Felser, A. Tanaka, C.T. Chen, and L.H. Tjeng |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1565756916 | ||
| 003 | DE-627 | ||
| 005 | 20220814032356.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 171128s2003 xx |||||o 00| ||eng c | ||
| 035 | |a (DE-627)1565756916 | ||
| 035 | |a (DE-576)495756911 | ||
| 035 | |a (DE-599)BSZ495756911 | ||
| 035 | |a (OCoLC)1340982650 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 29 |2 sdnb | ||
| 100 | 1 | |a Hu, Zhimin |d 1980- |e VerfasserIn |0 (DE-588)1140260758 |0 (DE-627)898442451 |0 (DE-576)493761055 |4 aut | |
| 245 | 1 | 2 | |a A different look at the spin state of Co3+ ions in CoO5 pyramidal coordination |c Z. Hu, Hua Wu, M.W. Haverkort, H.H. Hsieh, H.-J. Lin, T. Lorenz, J. Baier, A. Reichl, I. Bonn, C. Felser, A. Tanaka, C.T. Chen, and L.H. Tjeng |
| 264 | 1 | |c 2003 | |
| 300 | |a 5 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Titel ist "3+" hoch und "5" tiefgestellt | ||
| 500 | |a Gesehen am 28.11.2017 | ||
| 520 | |a Using soft-x-ray absorption spectroscopy at the Co-$L_{2,3}$ and O-$K$ edges, we demonstrate that the Co$^{3+}$ ions with the CoO$_{5}$ pyramidal coordination in the layered Sr$_2$CoO$_3$Cl compound are unambiguously in the high spin state. Our result questions the reliability of the spin state assignments made so far for the recently synthesized layered cobalt perovskites, and calls for a re-examination of the modeling for the complex and fascinating properties of these new materials. | ||
| 650 | 4 | |a Condensed Matter - Strongly Correlated Electrons | |
| 700 | 1 | |a Haverkort, Maurits W. |d 1976- |e VerfasserIn |0 (DE-588)130132047 |0 (DE-627)491717946 |0 (DE-576)257824006 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Arxiv |d Ithaca, NY : Cornell University, 1991 |g (2003) Artikel-Nummer 0310138, 5 Seiten |h Online-Ressource |w (DE-627)509006531 |w (DE-600)2225896-6 |w (DE-576)28130436X |7 nnas |a A different look at the spin state of Co3+ ions in CoO5 pyramidal coordination |
| 773 | 1 | 8 | |g year:2003 |g extent:5 |a A different look at the spin state of Co3+ ions in CoO5 pyramidal coordination |
| 856 | 4 | 0 | |u http://arxiv.org/abs/cond-mat/0310138 |x Verlag |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20171128 | ||
| 993 | |a Article | ||
| 998 | |g 130132047 |a Haverkort, Maurits W. |m 130132047:Haverkort, Maurits W. |p 3 | ||
| 999 | |a KXP-PPN1565756916 |e 298832557X | ||
| BIB | |a Y | ||
| JSO | |a {"relHost":[{"id":{"zdb":["2225896-6"],"eki":["509006531"]},"language":["eng"],"type":{"bibl":"edited-book","media":"Online-Ressource"},"origin":[{"publisherPlace":"Ithaca, NY ; [Erscheinungsort nicht ermittelbar]","dateIssuedDisp":"1991-","publisher":"Cornell University ; Arxiv.org","dateIssuedKey":"1991"}],"part":{"text":"(2003) Artikel-Nummer 0310138, 5 Seiten","year":"2003","extent":"5"},"title":[{"title_sort":"Arxiv","title":"Arxiv"}],"physDesc":[{"extent":"Online-Ressource"}],"titleAlt":[{"title":"Arxiv.org"},{"title":"Arxiv.org e-print archive"},{"title":"Arxiv e-print archive"},{"title":"De.arxiv.org"}],"disp":"A different look at the spin state of Co3+ ions in CoO5 pyramidal coordinationArxiv","recId":"509006531","pubHistory":["1991 -"],"note":["Gesehen am 28.05.2024"]}],"title":[{"title_sort":"different look at the spin state of Co3+ ions in CoO5 pyramidal coordination","title":"A different look at the spin state of Co3+ ions in CoO5 pyramidal coordination"}],"person":[{"family":"Hu","display":"Hu, Zhimin","given":"Zhimin","role":"aut"},{"display":"Haverkort, Maurits W.","family":"Haverkort","given":"Maurits W.","role":"aut"}],"physDesc":[{"extent":"5 S."}],"origin":[{"dateIssuedDisp":"2003","dateIssuedKey":"2003"}],"language":["eng"],"id":{"eki":["1565756916"]},"type":{"bibl":"chapter","media":"Online-Ressource"},"recId":"1565756916","note":["Im Titel ist \"3+\" hoch und \"5\" tiefgestellt","Gesehen am 28.11.2017"],"name":{"displayForm":["Z. Hu, Hua Wu, M.W. Haverkort, H.H. Hsieh, H.-J. Lin, T. Lorenz, J. Baier, A. Reichl, I. Bonn, C. Felser, A. Tanaka, C.T. Chen, and L.H. Tjeng"]}} | ||
| SRT | |a HUZHIMINHADIFFERENTL2003 | ||