The radical anion and dianion of tetraazapentacene
The mono- and bis-reduction of 6,13-bis((triisopropylsilyl)ethynyl)quinoxalino[2,3-b]phenazine (1) with potassium anthracenide in THF is reported. Both the radical anion 1.− and the dianion 12− were isolated and characterized by optical and structural (single-crystal X-ray diffraction) methods. Solu...
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| Main Authors: | , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
19 July 2016
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| In: |
Angewandte Chemie. International edition
Year: 2016, Volume: 55, Issue: 35, Pages: 10498-10501 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201603177 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/anie.201603177 Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/anie.201603177/abstract 
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| Author Notes: | Lei Ji, Martin Haehnel, Ivo Krummenacher, Philipp Biegger, Florian L. Geyer, Olena Tverskoy, Manuel Schaffroth, Jie Han, Andreas Dreuw, Todd B. Marder, and Uwe H. F. Bunz |
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| 520 | |a The mono- and bis-reduction of 6,13-bis((triisopropylsilyl)ethynyl)quinoxalino[2,3-b]phenazine (1) with potassium anthracenide in THF is reported. Both the radical anion 1.− and the dianion 12− were isolated and characterized by optical and structural (single-crystal X-ray diffraction) methods. Solutions of the radical anion 1.− were stable in air for several hours and characterized by EPR spectroscopy. Dianion 12− is highly fluorescent and photostable. | ||
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