The lamellar-to-isotropic transition in ternary amphiphilic systems
We study the dependence of the phase behavior of ternary amphiphilic systems on composition and temperature. Our analysis is based on a curvature elastic model of the surfactant film with sufficiently large spontaneous curvature and sufficiently negative saddle-splay modulus that the stable phases a...
Gespeichert in:
| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) Kapitel/Artikel |
| Sprache: | Englisch |
| Veröffentlicht: |
1996
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| In: |
Arxiv
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| Online-Zugang: | Verlag, kostenfrei, Volltext: http://arxiv.org/abs/cond-mat/9608157
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| Verfasserangaben: | U.S. Schwarz, K. Swamy and G. Gompper |
MARC
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| 100 | 1 | |a Schwarz, Ulrich S. |d 1966- |e VerfasserIn |0 (DE-588)120379473 |0 (DE-627)080637280 |0 (DE-576)297582763 |4 aut | |
| 245 | 1 | 4 | |a The lamellar-to-isotropic transition in ternary amphiphilic systems |c U.S. Schwarz, K. Swamy and G. Gompper |
| 264 | 1 | |c 1996 | |
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| 520 | |a We study the dependence of the phase behavior of ternary amphiphilic systems on composition and temperature. Our analysis is based on a curvature elastic model of the surfactant film with sufficiently large spontaneous curvature and sufficiently negative saddle-splay modulus that the stable phases are the lamellar phase and a droplet microemulsion. In addition to the curvature energy, we consider the contributions to the free energy of the long-ranged van der Waals interaction and of the undulation modes. We find that for bending rigidities of order k_B T, the lamellar phase extends further and further into the water apex of the phase diagram as the phase inversion temperature is approached, in good agreement with experimental results. | ||
| 650 | 4 | |a Condensed Matter | |
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| 700 | 1 | |a Gompper, Gerhard |d 1956- |e VerfasserIn |0 (DE-588)1150412232 |0 (DE-627)1010727338 |0 (DE-576)164693483 |4 aut | |
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