Gold(I) complexes of tetrathiaheterohelicene phosphanes
New tetrathia[7]helicene-based (7-TH-based) gold(I) complexes 6 and 7 have been readily prepared by reaction of the respective phosphine ligands 2 and 3 with Au(tht)Cl in a 1:1 and 1:2 molar ratio, respectively. These complexes have been fully characterized by analytical and spectroscopic techniques...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
July 1, 2013
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| In: |
Inorganic chemistry
Year: 2013, Volume: 52, Issue: 14, Pages: 7995-8004 |
| ISSN: | 1520-510X |
| DOI: | 10.1021/ic4005533 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1021/ic4005533 |
| Author Notes: | Silvia Cauteruccio, Annette Loos, Alberto Bossi, Maria Camila Blanco Jaimes, Davide Dova, Frank Rominger, Stefan Prager, Andreas Dreuw, Emanuela Licandro, and A. Stephen K. Hashmi |
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| 520 | |a New tetrathia[7]helicene-based (7-TH-based) gold(I) complexes 6 and 7 have been readily prepared by reaction of the respective phosphine ligands 2 and 3 with Au(tht)Cl in a 1:1 and 1:2 molar ratio, respectively. These complexes have been fully characterized by analytical and spectroscopic techniques as well as quantum chemical calculations. | ||
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