New chromium(III) complexes as highly active catalysts for olefin polymerization
Cyclopentadienyl ligands functionalized by quinoline or N,N-dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5-8 with intramolecular nitrogen coordination have been obtained. Treatment with MAO leads to highly...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2001
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| In: |
Organometallics
Year: 2001, Jahrgang: 20, Heft: 24, Pages: 5005-5007 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om010753 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1021/om010753+
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| Verfasserangaben: | Markus Enders, Pablo Fernández, Gunter Ludwig, Hans Pritzkow |
MARC
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| 520 | |a Cyclopentadienyl ligands functionalized by quinoline or N,N-dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5-8 with intramolecular nitrogen coordination have been obtained. Treatment with MAO leads to highly active, temperature-stable catalysts for the polymerization of ethylene. | ||
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