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New chromium(III) complexes as highly active catalysts for olefin polymerization

Cyclopentadienyl ligands functionalized by quinoline or N,N-dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5-8 with intramolecular nitrogen coordination have been obtained. Treatment with MAO leads to highly...

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Bibliographische Detailangaben
Hauptverfasser: Enders, Markus (VerfasserIn) , Fernández, Pablo (VerfasserIn) , Ludwig, Gunter (VerfasserIn) , Pritzkow, Hans (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2001
In: Organometallics
Year: 2001, Jahrgang: 20, Heft: 24, Pages: 5005-5007
ISSN:1520-6041
DOI:10.1021/om010753
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1021/om010753+
Volltext
Verfasserangaben:Markus Enders, Pablo Fernández, Gunter Ludwig, Hans Pritzkow
Beschreibung
Zusammenfassung:Cyclopentadienyl ligands functionalized by quinoline or N,N-dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5-8 with intramolecular nitrogen coordination have been obtained. Treatment with MAO leads to highly active, temperature-stable catalysts for the polymerization of ethylene.
Beschreibung:Gesehen am 19.02.2018
Beschreibung:Online Resource
ISSN:1520-6041
DOI:10.1021/om010753

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