Synthesis and coordination behaviour of the new (8-quinolyl)cyclopentadienyl ligand

8-Bromoquinoline reacts with zincated cyclopentadienyl derivatives of Fe, Mn, and Re in the presence of bis(triphenylphosphine)palladium(0) to yield the corresponding 8-quinolylcyclopentadienyl metal complexes. Tricarbonyl[eta (5)-(8-quinolyl)cyclopentadienyl]manganese(I) (5) and tricarbonyl[eta (5)...

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Hauptverfasser: Enders, Markus (VerfasserIn) , Kohl, Gerald (VerfasserIn) , Pritzkow, Hans (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2001
In: Journal of organometallic chemistry
Year: 2001, Jahrgang: 622, Heft: 1-2, Pages: 66-73
ISSN:1872-8561
DOI:10.1016/S0022-328X(00)00866-4
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1016/S0022-328X(00)00866-4
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Verfasserangaben:Markus Enders, Gerald Kohl, Hans Pritzkow

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520 |a 8-Bromoquinoline reacts with zincated cyclopentadienyl derivatives of Fe, Mn, and Re in the presence of bis(triphenylphosphine)palladium(0) to yield the corresponding 8-quinolylcyclopentadienyl metal complexes. Tricarbonyl[eta (5)-(8-quinolyl)cyclopentadienyl]manganese(I) (5) and tricarbonyl[eta (5)-(8-quinolyl)cyclopentadienyl]rhenium(I) (6) eliminate CO upon irradiation to form dicarbonyl[eta (5)-(8-quinolyl)cyclopentadienyl]manganese(I) (7) and dicarbonyl[eta (5)-(8-quinolyl)cyclopentadienyl]rhenium(I) (8), respectively. The intensely coloured complexes 7 and 8 show solvatochromism, which has been investigated in more detail. Coordination of the quinolyl moiety in 7 and 8 could be proved by spectroscopy and by crystal structure determination. 
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