Chirale titan- und zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3-dimethylcyclopentadienyl-Liganden
Reaction of 8-lithioquinoline with 2,3-dimethylcyclopent-2-en-1-one leads to 1-(8-quinolyl)-2,3-dimethyl-cyclopentadiene (1) after hydrolysis and H2O elimination in acidic solution. With strong bases 1 is deprotonated to the intensively red coloured anion 2.2 was converted to the trimethylsilyl deri...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
1997
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| In: |
Journal of organometallic chemistry
Year: 1997, Volume: 549, Issue: 1, Pages: 251-256 |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/S0022-328X(97)00503-2 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1016/S0022-328X(97)00503-2 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X97005032 
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| Author Notes: | Markus Enders, Ralph Rudolph, Hans Pritzkow |
| Summary: | Reaction of 8-lithioquinoline with 2,3-dimethylcyclopent-2-en-1-one leads to 1-(8-quinolyl)-2,3-dimethyl-cyclopentadiene (1) after hydrolysis and H2O elimination in acidic solution. With strong bases 1 is deprotonated to the intensively red coloured anion 2.2 was converted to the trimethylsilyl derivative 3, which could be characterized by crystal structure analysis, 3 reacts with group 4 transition metal chlorides to the chiral trichlorotitanium and trichlorozirconium complexes 4 and 5. 4 was examined by crystal structure analysis and shows the expected interaction between the quinolyl nitrogen atom and the metal centre. |
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| Item Description: | Gesehen am 28.02.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/S0022-328X(97)00503-2 |