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Synthese und Kristallstruktur von Pentakis(dimethylsulfoxid)- oxo-titan(IV)chlorid: Herrn Professor Dr. Walter Siebert zum 60. Geburtstag gewidmet = Synthesis and crystal structure of Pentakis(dimethylsulfoxide)-oxo-titanium(IV) chloride

Pentakis(dimethylsulfoxide)-oxo-titanium(IV) chloride is obtained by reaction of titanium tetrachloride with a stoichiometric amount of water in dimethylsulfoxide. A single crystal structure determination (P1̄, a = 9.564(6), b = 10.504(7), c = 12.510(8) Å, α = 70.21(5), β = 83.48(5), γ = 89.82(5)°,...

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Bibliographic Details
Main Authors: Enders, Markus (Author) , Rudolph, Ralph (Author) , Pritzkow, Hans (Author)
Format: Article (Journal) Festschrift
Language:English
German
Published: 1997
In: Zeitschrift für Naturforschung. B, a journal of chemical sciences
Year: 1997, Volume: 52, Issue: 4, Pages: 496-499
ISSN:1865-7117
DOI:10.1515/znb-1997-0411
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Festschrift
Online Access:Verlag, Volltext: http://dx.doi.org/10.1515/znb-1997-0411
Verlag, Volltext: https://www.degruyterbrill.com/view/j/znb.1997.52.issue-4/znb-1997-0411/znb-1997-0411.xml
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Author Notes:M. Enders, R. Rudolph, H. Pritzkow
Description
Summary:Pentakis(dimethylsulfoxide)-oxo-titanium(IV) chloride is obtained by reaction of titanium tetrachloride with a stoichiometric amount of water in dimethylsulfoxide. A single crystal structure determination (P1̄, a = 9.564(6), b = 10.504(7), c = 12.510(8) Å, α = 70.21(5), β = 83.48(5), γ = 89.82(5)°, V = 1174 Å3, Z = 2) shows a dicationic titanium(IV) complex with five dimethylsulfoxide ligands and one oxygen atom. The two chlorine anions are not bonded to the complex cation. The TiO6-fragment is a distorted octahedron, where five of the six oxygen atoms belong to the coordinated dimethylsulfoxide molecules.
Item Description:Gesehen am 28.02.2018
Physical Description:Online Resource
ISSN:1865-7117
DOI:10.1515/znb-1997-0411

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