Trends in base hydrolysis rates of Chlorocobalt(III) complexes of a series of related Pentaamine ligands
Base hydrolysis kinetics of chloropentaaminecobalt(III) complexes of a range of acyclic and cyclic pentaamine ligands, incorporating the rigid -NH-CH 2 -C(CH 3 )(NH 2 )-CH 2 -NH- motif, which must coordinate facially in octahedral complexes, are analysed in terms of ground state structural influence...
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2002
|
| In: |
Inorganic reaction mechanisms
Year: 2002, Jahrgang: 4, Heft: 1-2, Pages: 31-47 |
| ISSN: | 1607-8470 |
| DOI: | 10.1080/1028662021000062509 |
| Online-Zugang: | Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1080/1028662021000062509 Verlag, Pay-per-use, Volltext: https://doi.org/10.1080/1028662021000062509 |
| Verfasserangaben: | Yakup Baran, Peter Comba & Geoffrey A. Lawrance |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1570396698 | ||
| 003 | DE-627 | ||
| 005 | 20220814084538.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180305s2002 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1080/1028662021000062509 |2 doi | |
| 035 | |a (DE-627)1570396698 | ||
| 035 | |a (DE-576)500396698 | ||
| 035 | |a (DE-599)BSZ500396698 | ||
| 035 | |a (OCoLC)1340993930 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Baran, Yakup |e VerfasserIn |0 (DE-588)1153737965 |0 (DE-627)1015237398 |0 (DE-576)50039797X |4 aut | |
| 245 | 1 | 0 | |a Trends in base hydrolysis rates of Chlorocobalt(III) complexes of a series of related Pentaamine ligands |c Yakup Baran, Peter Comba & Geoffrey A. Lawrance |
| 264 | 1 | |c 2002 | |
| 300 | |a 17 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Article was published online on 18 Oct 2010 | ||
| 500 | |a Gesehen am 05.03.2018 | ||
| 520 | |a Base hydrolysis kinetics of chloropentaaminecobalt(III) complexes of a range of acyclic and cyclic pentaamine ligands, incorporating the rigid -NH-CH 2 -C(CH 3 )(NH 2 )-CH 2 -NH- motif, which must coordinate facially in octahedral complexes, are analysed in terms of ground state structural influences on hydrolysis rates. For complexes without experimental structural data, molecular mechanics was used to predict Co-Cl and Co-N bond distances. The computed strain energies and structural parameters both isomers ( trans and cis ) of all compounds are analysed. Although sterically crowded ligands, which should favour a five-coordinate intermediate, exhibit larger k OH values, only a modest correlation between ground state Co-L distances and hydrolysis rates is found. This suggests that the structures of the transition state and/or of the five-coordinate intermediate is important. | ||
| 650 | 4 | |a Base Hydrolysis Kinetics | |
| 650 | 4 | |a Cobalt(III) | |
| 650 | 4 | |a Molecular Modelling | |
| 650 | 4 | |a Polyamines | |
| 700 | 1 | |a Comba, Peter |d 1953- |e VerfasserIn |0 (DE-588)122976843 |0 (DE-627)082271712 |0 (DE-576)160608988 |4 aut | |
| 700 | 1 | |a Lawrance, Geoffrey A. |e VerfasserIn |0 (DE-588)1153738511 |0 (DE-627)1015238416 |0 (DE-576)310430372 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Inorganic reaction mechanisms |d Philadelphia, Pa. : Old City Publishing, 2002 |g 4(2002), 1-2, Seite 31-47 |h Online-Ressource |w (DE-627)325350213 |w (DE-600)2035623-7 |w (DE-576)339259957 |x 1607-8470 |7 nnas |a Trends in base hydrolysis rates of Chlorocobalt(III) complexes of a series of related Pentaamine ligands |
| 773 | 1 | 8 | |g volume:4 |g year:2002 |g number:1-2 |g pages:31-47 |g extent:17 |a Trends in base hydrolysis rates of Chlorocobalt(III) complexes of a series of related Pentaamine ligands |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1080/1028662021000062509 |x Verlag |x Resolving-System |z Pay-per-use |3 Volltext |
| 856 | 4 | 0 | |u https://doi.org/10.1080/1028662021000062509 |x Verlag |z Pay-per-use |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20180305 | ||
| 993 | |a Article | ||
| 994 | |a 2002 | ||
| 998 | |g 122976843 |a Comba, Peter |m 122976843:Comba, Peter |d 120000 |d 120200 |e 120000PC122976843 |e 120200PC122976843 |k 0/120000/ |k 1/120000/120200/ |p 2 | ||
| 999 | |a KXP-PPN1570396698 |e 3001635134 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"name":{"displayForm":["Yakup Baran, Peter Comba & Geoffrey A. Lawrance"]},"note":["Article was published online on 18 Oct 2010","Gesehen am 05.03.2018"],"recId":"1570396698","title":[{"title_sort":"Trends in base hydrolysis rates of Chlorocobalt(III) complexes of a series of related Pentaamine ligands","title":"Trends in base hydrolysis rates of Chlorocobalt(III) complexes of a series of related Pentaamine ligands"}],"person":[{"family":"Baran","display":"Baran, Yakup","given":"Yakup","role":"aut"},{"given":"Peter","display":"Comba, Peter","family":"Comba","role":"aut"},{"role":"aut","given":"Geoffrey A.","display":"Lawrance, Geoffrey A.","family":"Lawrance"}],"physDesc":[{"extent":"17 S."}],"relHost":[{"title":[{"title_sort":"Inorganic reaction mechanisms","title":"Inorganic reaction mechanisms"}],"physDesc":[{"extent":"Online-Ressource"}],"part":{"issue":"1-2","year":"2002","extent":"17","pages":"31-47","text":"4(2002), 1-2, Seite 31-47","volume":"4"},"origin":[{"publisher":"Old City Publishing ; Taylor & Francis","dateIssuedKey":"2002","publisherPlace":"Philadelphia, Pa. ; London [u.a.]","dateIssuedDisp":"2002-2002"}],"id":{"eki":["325350213"],"zdb":["2035623-7"],"issn":["1607-8470"]},"type":{"bibl":"periodical","media":"Online-Ressource"},"language":["eng"],"pubHistory":["Nachgewiesen 3.2002,3 - 4.2002"],"recId":"325350213","note":["Gesehen am 28.07.2021"],"disp":"Trends in base hydrolysis rates of Chlorocobalt(III) complexes of a series of related Pentaamine ligandsInorganic reaction mechanisms"}],"language":["eng"],"id":{"eki":["1570396698"],"doi":["10.1080/1028662021000062509"]},"type":{"media":"Online-Ressource","bibl":"article-journal"},"origin":[{"dateIssuedKey":"2002","dateIssuedDisp":"2002"}]} | ||
| SRT | |a BARANYAKUPTRENDSINBA2002 | ||