Solid-state and solution structural properties of copper(I) compounds with bidentate phosphane ligands
The copper(I) compounds [Cu(dppe)2]X [X = BF4−, I−; dppe = 1,2-bis(diphenylphosphanyl)ethane], [Cu(dppp)2]X [X = BF4−,I−; dppp = 1,3-bis(diphenylphosphanyl)propane], [Cu2(dppe)3I2], and [Cu2(dppe)2I2] have been prepared and their structural properties in solution and in the solid state have been det...
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| 1. Verfasser: | |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
15 April 1999
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| In: |
European journal of inorganic chemistry
Year: 1999, Heft: 5, Pages: 777-783 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/(SICI)1099-0682(199905)1999:5<777::AID-EJIC777>3.0.CO;2-A |
| Online-Zugang: | Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1002/(SICI)1099-0682(199905)1999:5<777::AID-EJIC777>3.0.CO;2-A Verlag, Pay-per-use, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1099-0682(199905)1999:5<777::AID-EJIC777>3.0.CO;2-A/abstract |
| Verfasserangaben: | Peter Comba, Charis Katsichtis, Bernd Nuber, and Hans Pritzkow |
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| 245 | 1 | 0 | |a Solid-state and solution structural properties of copper(I) compounds with bidentate phosphane ligands |c Peter Comba, Charis Katsichtis, Bernd Nuber, and Hans Pritzkow |
| 264 | 1 | |c 15 April 1999 | |
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| 520 | |a The copper(I) compounds [Cu(dppe)2]X [X = BF4−, I−; dppe = 1,2-bis(diphenylphosphanyl)ethane], [Cu(dppp)2]X [X = BF4−,I−; dppp = 1,3-bis(diphenylphosphanyl)propane], [Cu2(dppe)3I2], and [Cu2(dppe)2I2] have been prepared and their structural properties in solution and in the solid state have been determined. 1H-, 13C-, and 31P-NMR spectra in solution [variable temperature and anion (I−) concentrations] and analyses of solids (mass spectra, elemental analyses, and CPMAS 31P-NMR spectra) are interpreted with equilibria in solution that involve two mono- and two dinuclear species. The structures of [Cu(dppe)2]ClO4, [Cu(dppp)2]BF4, and [Cu2(dppe)3I2] · 2 CHCl3 have been analyzed by X-ray crystallography. In all three structures the copper(I) center adopts a distorted tetrahedral geometry. | ||
| 650 | 4 | |a coordination chemistry | |
| 650 | 4 | |a copper | |
| 650 | 4 | |a NMR spectroscopy | |
| 650 | 4 | |a Phosphane | |
| 650 | 4 | |a P ligands | |
| 650 | 4 | |a Solution structure | |
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