The figure-of-eight twist to macrocycles: preorganization, self-organization and dynamics
Large macrocyclic rings (30- to 36-membered) with two dithiadiimine donor sets and two para- or meta-phenylene spacer groups undergo copper(I) induced folding with π stacking of the two benzene spacer groups. The type of folding (twisted to a helical or squeezed to an achiral macrocyclic shape) and...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
1999
|
| In: |
Dalton transactions
Year: 1999, Issue: 4, Pages: 509-516 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/A806075D |
| Online Access: | Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1039/A806075D Verlag, Pay-per-use, Volltext: http://pubs.rsc.org/en/content/articlelanding/1999/dt/a806075d 
|
| Author Notes: | Peter Comba, Andreas Kühner and Alexander Peters |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1571023313 | ||
| 003 | DE-627 | ||
| 005 | 20220814092215.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180313s1999 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1039/A806075D |2 doi | |
| 035 | |a (DE-627)1571023313 | ||
| 035 | |a (DE-576)501023313 | ||
| 035 | |a (DE-599)BSZ501023313 | ||
| 035 | |a (OCoLC)1340994294 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Comba, Peter |d 1953- |e VerfasserIn |0 (DE-588)122976843 |0 (DE-627)082271712 |0 (DE-576)160608988 |4 aut | |
| 245 | 1 | 4 | |a The figure-of-eight twist to macrocycles |b preorganization, self-organization and dynamics |c Peter Comba, Andreas Kühner and Alexander Peters |
| 264 | 1 | |c 1999 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 13.03.2018 | ||
| 520 | |a Large macrocyclic rings (30- to 36-membered) with two dithiadiimine donor sets and two para- or meta-phenylene spacer groups undergo copper(I) induced folding with π stacking of the two benzene spacer groups. The type of folding (twisted to a helical or squeezed to an achiral macrocyclic shape) and the stability of the dicopper(I) compounds are analysed as a function of the ligand structure, the solid state structures, solution equilibria and dynamics and the comparison of the observed data with computed structures and conformational equilibria. Preliminary preparative studies suggest that derivatives with the observed structural motifs may be used to build heterometallic oligonuclear arrays. | ||
| 700 | 1 | |a Kühner, Andreas |e VerfasserIn |0 (DE-588)115446699X |0 (DE-627)1015769934 |0 (DE-576)501024565 |4 aut | |
| 700 | 1 | |a Peters, Alexander |e VerfasserIn |0 (DE-588)1154467260 |0 (DE-627)1015770398 |0 (DE-576)501025057 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Dalton transactions |d Cambridge : Royal Society of Chemistry, 2003 |g (1999), 4, Seite 509-516 |h Online-Ressource |w (DE-627)268759146 |w (DE-600)1472887-4 |w (DE-576)077609883 |x 1477-9234 |7 nnas |a The figure-of-eight twist to macrocycles preorganization, self-organization and dynamics |
| 773 | 1 | 8 | |g year:1999 |g number:4 |g pages:509-516 |g extent:8 |a The figure-of-eight twist to macrocycles preorganization, self-organization and dynamics |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1039/A806075D |x Verlag |x Resolving-System |z Pay-per-use |3 Volltext |
| 856 | 4 | 0 | |u http://pubs.rsc.org/en/content/articlelanding/1999/dt/a806075d |x Verlag |z Pay-per-use |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20180313 | ||
| 993 | |a Article | ||
| 994 | |a 1999 | ||
| 998 | |g 122976843 |a Comba, Peter |m 122976843:Comba, Peter |d 120000 |d 120200 |e 120000PC122976843 |e 120200PC122976843 |k 0/120000/ |k 1/120000/120200/ |p 1 |x j | ||
| 999 | |a KXP-PPN1571023313 |e 3003131982 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"name":{"displayForm":["Peter Comba, Andreas Kühner and Alexander Peters"]},"note":["Gesehen am 13.03.2018"],"recId":"1571023313","title":[{"title":"The figure-of-eight twist to macrocycles","subtitle":"preorganization, self-organization and dynamics","title_sort":"figure-of-eight twist to macrocycles"}],"person":[{"role":"aut","given":"Peter","display":"Comba, Peter","family":"Comba"},{"given":"Andreas","family":"Kühner","display":"Kühner, Andreas","role":"aut"},{"role":"aut","family":"Peters","display":"Peters, Alexander","given":"Alexander"}],"physDesc":[{"extent":"8 S."}],"relHost":[{"corporate":[{"display":"Royal Society of Chemistry","role":"isb"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"language":["eng"],"id":{"zdb":["1472887-4"],"issn":["1477-9234"],"eki":["268759146"]},"note":["Gesehen am 30.01.25"],"pubHistory":["2003, issue 1 (2003)-"],"recId":"268759146","name":{"displayForm":["Royal Society of Chemistry"]},"disp":"The figure-of-eight twist to macrocycles preorganization, self-organization and dynamicsDalton transactions","part":{"extent":"8","year":"1999","issue":"4","text":"(1999), 4, Seite 509-516","pages":"509-516"},"title":[{"subtitle":"a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry","title":"Dalton transactions","title_sort":"Dalton transactions"}],"physDesc":[{"extent":"Online-Ressource"}],"origin":[{"dateIssuedKey":"2003","publisher":"Royal Society of Chemistry","dateIssuedDisp":"2003-","publisherPlace":"Cambridge"}]}],"id":{"doi":["10.1039/A806075D"],"eki":["1571023313"]},"type":{"bibl":"article-journal","media":"Online-Ressource"},"language":["eng"],"origin":[{"dateIssuedDisp":"1999","dateIssuedKey":"1999"}]} | ||
| SRT | |a COMBAPETERFIGUREOFEI1999 | ||