Cleavage of the N2 triple bond by the Ti dimer: a route to molecular materials for dinitrogen activation?
The Ti dimer is fairly weakly bound, but highly reactive, and completely cleaves the strong N2 triple bond in just one step without activation energy (see scheme; Ti red, N blue).
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2006
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| In: |
Angewandte Chemie. International edition
Year: 2006, Jahrgang: 45, Heft: 17, Pages: 2799-2802 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200503709 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/anie.200503709 Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/anie.200503709/full 
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| Verfasserangaben: | Hans-Jörg Himmel, Olaf Hübner, Wim Klopper, Laurent Manceron |
| Zusammenfassung: | The Ti dimer is fairly weakly bound, but highly reactive, and completely cleaves the strong N2 triple bond in just one step without activation energy (see scheme; Ti red, N blue). |
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| Beschreibung: | Gesehen am 14.03.2018 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200503709 |