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Tri(supersilyl)dialanyl (tBu3Si)3Al2• and tetra(supersilyl)cyclotrialanyl (tBu3Si)4Al3•: new stable radicals of a group 13 element from thermolysis of (tBu3Si)4Al2

The thermolysis of tetra(supersilyl)dialane R*2Al−AlR*2 (R* = SitBu3 = Supersilyl) in heptane or cyclohexane at 50 °C leads under Al−Al dissociation reversibly to monoalanyl radicals [R*2Al]•, which could...

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Bibliographische Detailangaben
Hauptverfasser: Wiberg, Nils (VerfasserIn) , Blank, Thomas (VerfasserIn) , Kaim, Wolfgang (VerfasserIn) , Schwederski, Brigitte (VerfasserIn) , Linti, Gerald W. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 4 July 2000
In: European journal of inorganic chemistry
Year: 2000, Heft: 7, Pages: 1475-1481
ISSN:1099-0682
DOI:10.1002/1099-0682(200007)2000:7<1475::AID-EJIC1475>3.0.CO;2-N
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1002/1099-0682(200007)2000:7<1475::AID-EJIC1475>3.0.CO;2-N
Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/1099-0682(200007)2000:7<1475::AID-EJIC1475>3.0.CO;2-N/full
Volltext
Verfasserangaben:Nils Wiberg, Thomas Blank, Wolfgang Kaim, Brigitte Schwederski, Gerald Linti

MARC

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