Substrate‐directed diastereoselective hydroformylation: key step for the assembly of polypropionate subunits

Abstract o-DPPB-Directed hydroformylation could serve as a key step for the construction of bifunctionalized stereotriad building blocks, which form the basis of polyketide natural products (see scheme). The prepared building blocks are well suited to permit polyketide chain extensions into both dir...

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Hauptverfasser: Breit, Bernhard (VerfasserIn) , Dauber, Mario (VerfasserIn) , Harms, Klaus (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 24 September 1999
In: Chemistry - a European journal
Year: 1999, Jahrgang: 5, Heft: 10, Pages: 2819-2827
ISSN:1521-3765
DOI:10.1002/(SICI)1521-3765(19991001)5:10<2819::AID-CHEM2819>3.0.CO;2-Z
Online-Zugang:Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1002/(SICI)1521-3765(19991001)5:10<2819::AID-CHEM2819>3.0.CO;2-Z
Verlag, Pay-per-use, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3765%2819991001%295%3A10%3C2819%3A%3AAID-CHEM2819%3E3.0.CO%3B2-Z
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Verfasserangaben:Bernhard Breit, Mario Dauber, and Klaus Harms
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Zusammenfassung:Abstract o-DPPB-Directed hydroformylation could serve as a key step for the construction of bifunctionalized stereotriad building blocks, which form the basis of polyketide natural products (see scheme). The prepared building blocks are well suited to permit polyketide chain extensions into both directions of the main chain. o-DPPB=ortho-diphenylphosphanylbenzoyl.
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Beschreibung:Online Resource
ISSN:1521-3765
DOI:10.1002/(SICI)1521-3765(19991001)5:10<2819::AID-CHEM2819>3.0.CO;2-Z