Domino hydroformylation‐Wittig reactions
Abstract Methallyl and homomethallyl alcohols can undergo stereoselective hydroformylation-Wittig and hydroformylation-Wittig-hydrogenation reactions in one-pot domino processes. This sequential transformation allows the formation of C-C bonds and the generation of a new stereogenic center, and give...
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| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
26 March 1999
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| In: |
Angewandte Chemie. International edition
Year: 1999, Jahrgang: 38, Heft: 7, Pages: 969-971 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/(SICI)1521-3773(19990401)38:7<969::AID-ANIE969>3.0.CO;2-4 |
| Online-Zugang: | Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1002/(SICI)1521-3773(19990401)38:7<969::AID-ANIE969>3.0.CO;2-4 Verlag, Pay-per-use, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3773%2819990401%2938%3A7%3C969%3A%3AAID-ANIE969%3E3.0.CO%3B2-4 
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| Verfasserangaben: | Bernhard Breit and Stephan K. Zahn |
| Zusammenfassung: | Abstract Methallyl and homomethallyl alcohols can undergo stereoselective hydroformylation-Wittig and hydroformylation-Wittig-hydrogenation reactions in one-pot domino processes. This sequential transformation allows the formation of C-C bonds and the generation of a new stereogenic center, and gives preparatively interesting compounds [Eq. (a)]. The reaction products are obtained in satisfactory to good yields and in diastereoselectivities of 90:10 to >98:2. CDG=catalyst-directing group; R'=H; R''=OEt, Me. |
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| Beschreibung: | Gesehen am 21.03.2018 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/(SICI)1521-3773(19990401)38:7<969::AID-ANIE969>3.0.CO;2-4 |