Relative thermal stability of Thiolate- and Selenolate-bonded aromatic monolayers on the Au(111) substrate

The thermal stability of self-assembled monolayers (SAMs) is of fundamental importance for the majority of their applications. It strongly depends on the type of chemical group used for bonding the molecules forming the SAMs to the selected substrate. Here, we compare the impact of using S and Se bo...

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Hauptverfasser: Ossowski, Jakub (VerfasserIn) , Zharnikov, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: November 24, 2017
In: The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2017, Jahrgang: 121, Heft: 50, Pages: 28031-28042
ISSN:1932-7455
DOI:10.1021/acs.jpcc.7b09685
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1021/acs.jpcc.7b09685
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Verfasserangaben:Jakub Ossowski, Giulia Nascimbeni, Tomasz Żaba, Elisabeth Verwüster, Jakub Rysz, Andreas Terfort, Michael Zharnikov, Egbert Zojer, and Piotr Cyganik
Beschreibung
Zusammenfassung:The thermal stability of self-assembled monolayers (SAMs) is of fundamental importance for the majority of their applications. It strongly depends on the type of chemical group used for bonding the molecules forming the SAMs to the selected substrate. Here, we compare the impact of using S and Se bonding groups on the thermal stability of aromatic model SAMs based on naphthalene, containing a polar substituent, and formed on a Au(111) substrate.
Beschreibung:Gesehen am 09.04.2018
Beschreibung:Online Resource
ISSN:1932-7455
DOI:10.1021/acs.jpcc.7b09685