Relative thermal stability of Thiolate- and Selenolate-bonded aromatic monolayers on the Au(111) substrate
The thermal stability of self-assembled monolayers (SAMs) is of fundamental importance for the majority of their applications. It strongly depends on the type of chemical group used for bonding the molecules forming the SAMs to the selected substrate. Here, we compare the impact of using S and Se bo...
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| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
November 24, 2017
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| In: |
The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2017, Jahrgang: 121, Heft: 50, Pages: 28031-28042 |
| ISSN: | 1932-7455 |
| DOI: | 10.1021/acs.jpcc.7b09685 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1021/acs.jpcc.7b09685
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| Verfasserangaben: | Jakub Ossowski, Giulia Nascimbeni, Tomasz Żaba, Elisabeth Verwüster, Jakub Rysz, Andreas Terfort, Michael Zharnikov, Egbert Zojer, and Piotr Cyganik |
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| 520 | |a The thermal stability of self-assembled monolayers (SAMs) is of fundamental importance for the majority of their applications. It strongly depends on the type of chemical group used for bonding the molecules forming the SAMs to the selected substrate. Here, we compare the impact of using S and Se bonding groups on the thermal stability of aromatic model SAMs based on naphthalene, containing a polar substituent, and formed on a Au(111) substrate. | ||
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