Synthesis and structures of the triple-decker type complexes CpCo([mu]1,3-C3B2Me5)MX2L (M = Rh and Ir; X = Cl and Br; L = Me2SO and PPh3)
The dimeric triple-decker type halides [CpCo(μ-1,3-C3B2Me5)MX2]2 (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(μ-1,3-C3B2Me5)M(L)X2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
September 2012
|
| In: |
Journal of organometallic chemistry
Year: 2012, Jahrgang: 715, Pages: 136-140 |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/j.jorganchem.2012.06.003 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1016/j.jorganchem.2012.06.003 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X12003294 
|
| Verfasserangaben: | Alexander S. Romanov, Dmitry V. Muratov, Mikhail Yu. Antipin, Walter Siebert, Alexander R. Kudinov |
| Zusammenfassung: | The dimeric triple-decker type halides [CpCo(μ-1,3-C3B2Me5)MX2]2 (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(μ-1,3-C3B2Me5)M(L)X2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone it is O-bonded. Structures of 5-12 were confirmed by X-ray diffraction. |
|---|---|
| Beschreibung: | Im Titel ist mu als griechischer Buchstabe dargestellt Gesehen am 11.04.2018 |
| Beschreibung: | Online Resource |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/j.jorganchem.2012.06.003 |