Synthesis and structures of the triple-decker type complexes CpCo([mu]1,3-C3B2Me5)MX2L (M = Rh and Ir; X = Cl and Br; L = Me2SO and PPh3)

The dimeric triple-decker type halides [CpCo(μ-1,3-C3B2Me5)MX2]2 (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(μ-1,3-C3B2Me5)M(L)X2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone...

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Hauptverfasser:	Romanov, Alexander S. (VerfasserIn) , Siebert, Walter (VerfasserIn)
Dokumenttyp:	Article (Journal)
Sprache:	Englisch
Veröffentlicht:	September 2012
In:	Journal of organometallic chemistry Year: 2012, Jahrgang: 715, Pages: 136-140
ISSN:	1872-8561
DOI:	10.1016/j.jorganchem.2012.06.003
Online-Zugang:	Verlag, Volltext: http://dx.doi.org/10.1016/j.jorganchem.2012.06.003 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X12003294
Verfasserangaben:	Alexander S. Romanov, Dmitry V. Muratov, Mikhail Yu. Antipin, Walter Siebert, Alexander R. Kudinov

The first triple-decker complex with the PtMe3 fragment: CpCo([mu]-1,3-C3B2Me5)PtMe3 von Romanov, Alexander S. (VerfasserIn) , Siebert, Walter (VerfasserIn) ,

in: Mendeleev communications, 22 (2012), 1, Seite 13-14

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Synthesis and structures of the triple-decker type complexes CpCo([mu]1,3-C3B2Me5)MX2L (M = Rh and Ir; X = Cl and Br; L = Me2SO and PPh3)

The first triple-decker complex with the PtMe3 fragment: CpCo([mu]-1,3-C3B2Me5)PtMe3 von Romanov, Alexander S. (VerfasserIn) , Siebert, Walter (VerfasserIn) ,

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