The first triple-decker complex with the PtMe3 fragment: CpCo([mu]-1,3-C3B2Me5)PtMe3
The μ-diborolyl triple-decker complex CpCo(μ-1,3-C3B2Me5)PtMe3 was prepared by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]-with [PtMe3I]4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C3B2Me5)]- and [PtMe3]+ fragments are ∼64% electrostatic and 36%...
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| Main Authors: | , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
January–February 2012
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| In: |
Mendeleev communications
Year: 2012, Volume: 22, Issue: 1, Pages: 13-14 |
| ISSN: | 1364-551X |
| DOI: | 10.1016/j.mencom.2012.01.004 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1016/j.mencom.2012.01.004 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0959943612000053 
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| Author Notes: | Alexander S. Romanov, Dmitry V. Muratov, Pavel V. Petrovskii, Walter Siebert, Alexander R. Kudinov |
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| 520 | |a The μ-diborolyl triple-decker complex CpCo(μ-1,3-C3B2Me5)PtMe3 was prepared by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]-with [PtMe3I]4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C3B2Me5)]- and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent. | ||
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