The first triple-decker complex with the PtMe3 fragment: CpCo([mu]-1,3-C3B2Me5)PtMe3

The μ-diborolyl triple-decker complex CpCo(μ-1,3-C3B2Me5)PtMe3 was prepared by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]-with [PtMe3I]4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C3B2Me5)]- and [PtMe3]+ fragments are ∼64% electrostatic and 36%...

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Bibliographic Details
Main Authors: Romanov, Alexander S. (Author) , Siebert, Walter (Author)
Format: Article (Journal)
Language:English
Published: January–February 2012
In: Mendeleev communications
Year: 2012, Volume: 22, Issue: 1, Pages: 13-14
ISSN:1364-551X
DOI:10.1016/j.mencom.2012.01.004
Online Access:Verlag, Volltext: http://dx.doi.org/10.1016/j.mencom.2012.01.004
Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0959943612000053
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Author Notes:Alexander S. Romanov, Dmitry V. Muratov, Pavel V. Petrovskii, Walter Siebert, Alexander R. Kudinov
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