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Ruthenium η4-trimethylenemethane complexes containing tripodal phosphanomethylamine ligands

Ruthenium η4-trimethylenemethane complexes containing two different tridentate phosphine ligands have been synthesized. The formation of the complexes using [Ru(η4-COD)(η3-CH2CMeCH2)2] as the metal precursor occurred via elimination of isobutene. An intermediate species has been isolated in which th...

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Bibliographic Details
Main Authors: Scherl, Peter (Author) , Kruckenberg, Achim (Author) , Mader, Steffen (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: September 20, 2012
In: Organometallics
Year: 2012, Volume: 31, Issue: 19, Pages: 7024-7027
ISSN:1520-6041
DOI:10.1021/om300794h
Online Access:Verlag, Volltext: http://dx.doi.org/10.1021/om300794h
Verlag, Volltext: https://doi.org/10.1021/om300794h
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Author Notes:Peter Scherl, Achim Kruckenberg, Steffen Mader, Hubert Wadepohl, and Lutz H. Gade
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Summary:Ruthenium η4-trimethylenemethane complexes containing two different tridentate phosphine ligands have been synthesized. The formation of the complexes using [Ru(η4-COD)(η3-CH2CMeCH2)2] as the metal precursor occurred via elimination of isobutene. An intermediate species has been isolated in which the ligand coordinates with only two phosphorus atoms. Furthermore, protonation of the trimethylenemethane ligand gave rise to a cationic methylallyl complex.
Item Description:Gesehen am 23.04.2018
Im Titel ist [eta] als griechischer Buchstabe dargestellt
Im Titel ist "4" hochgestellt
Physical Description:Online Resource
ISSN:1520-6041
DOI:10.1021/om300794h

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