Ruthenium η4-trimethylenemethane complexes containing tripodal phosphanomethylamine ligands
Ruthenium η4-trimethylenemethane complexes containing two different tridentate phosphine ligands have been synthesized. The formation of the complexes using [Ru(η4-COD)(η3-CH2CMeCH2)2] as the metal precursor occurred via elimination of isobutene. An intermediate species has been isolated in which th...
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| Main Authors: | , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
September 20, 2012
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| In: |
Organometallics
Year: 2012, Volume: 31, Issue: 19, Pages: 7024-7027 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om300794h |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1021/om300794h Verlag, Volltext: https://doi.org/10.1021/om300794h |
| Author Notes: | Peter Scherl, Achim Kruckenberg, Steffen Mader, Hubert Wadepohl, and Lutz H. Gade |
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| 520 | |a Ruthenium η4-trimethylenemethane complexes containing two different tridentate phosphine ligands have been synthesized. The formation of the complexes using [Ru(η4-COD)(η3-CH2CMeCH2)2] as the metal precursor occurred via elimination of isobutene. An intermediate species has been isolated in which the ligand coordinates with only two phosphorus atoms. Furthermore, protonation of the trimethylenemethane ligand gave rise to a cationic methylallyl complex. | ||
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