Ruthenium η4-trimethylenemethane complexes containing tripodal phosphanomethylamine ligands
Ruthenium η4-trimethylenemethane complexes containing two different tridentate phosphine ligands have been synthesized. The formation of the complexes using [Ru(η4-COD)(η3-CH2CMeCH2)2] as the metal precursor occurred via elimination of isobutene. An intermediate species has been isolated in which th...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
September 20, 2012
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| In: |
Organometallics
Year: 2012, Jahrgang: 31, Heft: 19, Pages: 7024-7027 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om300794h |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1021/om300794h Verlag, Volltext: https://doi.org/10.1021/om300794h |
| Verfasserangaben: | Peter Scherl, Achim Kruckenberg, Steffen Mader, Hubert Wadepohl, and Lutz H. Gade |
| Zusammenfassung: | Ruthenium η4-trimethylenemethane complexes containing two different tridentate phosphine ligands have been synthesized. The formation of the complexes using [Ru(η4-COD)(η3-CH2CMeCH2)2] as the metal precursor occurred via elimination of isobutene. An intermediate species has been isolated in which the ligand coordinates with only two phosphorus atoms. Furthermore, protonation of the trimethylenemethane ligand gave rise to a cationic methylallyl complex. |
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| Beschreibung: | Gesehen am 23.04.2018 Im Titel ist [eta] als griechischer Buchstabe dargestellt Im Titel ist "4" hochgestellt |
| Beschreibung: | Online Resource |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om300794h |