Ruthenium-catalyzed deaminative hydrogenation of aliphatic and aromatic nitriles to primary alcohols
The deaminative hydrogenation of nitriles towards alcohols is a useful reaction to transform nitriles into alcohols with NH3 as the sole byproduct. Using the simple and robust RuHCl(CO)(PPh3)3 complex as a catalyst, at low H2 pressures a series of aliphatic and aromatic nitriles could be transformed...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
4 July 2017
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| In: |
ChemCatChem
Year: 2017, Jahrgang: 9, Heft: 22, Pages: 4175-4178 |
| ISSN: | 1867-3899 |
| DOI: | 10.1002/cctc.201700878 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/cctc.201700878 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201700878 
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| Verfasserangaben: | István Gábor Molnár, Pilar Calleja, Martin Ernst, A. Stephen K. Hashmi, Thomas Schaub |
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| 520 | |a The deaminative hydrogenation of nitriles towards alcohols is a useful reaction to transform nitriles into alcohols with NH3 as the sole byproduct. Using the simple and robust RuHCl(CO)(PPh3)3 complex as a catalyst, at low H2 pressures a series of aliphatic and aromatic nitriles could be transformed into the corresponding alcohols. Suitable solvent systems for these reactions were 1,4-dioxane/water and EtOH/water mixtures. In most cases, the selectivity for the alcohols was excellent, and the corresponding amines were formed only in trace amounts. | ||
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