The solid-state, solution and gas-phase interactions of diphosphane monooxide spacers with heavier group 8,9 transition metals and gallium in novel organometallic assemblies: An experimental and computational study
Six new mono-substituted carbonyl clusters [M3(CO)11(DPMO)] (M = Os, Ru; 1-4) and [Rh6(CO)15(DPMO)] (5, 6) were obtained from the reactions of non-symmetrical bifunctional diphosphane monoxides (DPMOs, Ph2P(CH2)nP(O)Ph2, n = 2, 3) with triangular clusters [Os3(CO)12] and [Ru3(CO)12], and octahedral...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
1 September 2012
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| In: |
Journal of organometallic chemistry
Year: 2012, Volume: 714, Pages: 22-31 |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/j.jorganchem.2012.03.003 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1016/j.jorganchem.2012.03.003 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X12001350 
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| Author Notes: | Kirill Yu. Monakhov, Elena V. Grachova, Galina L. Starova, Thomas Zessin, Gerald Linti |