Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite
Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN2(N-N) unit.
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
25 Jan 2012
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| In: |
Chemical communications
Year: 2012, Jahrgang: 48, Heft: 18, Pages: 2397-2399 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C2CC17594K |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1039/C2CC17594K Verlag, Volltext: http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc17594k 
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| Verfasserangaben: | Thorsten Gehrmann, Matthias Kruck, Hubert Wadepohl and Lutz H. Gade |
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| 520 | |a Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN2(N-N) unit. | ||
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