Metal-free nitrile diboration through activation by an electron-rich diborane
Diboration of unsaturated organic compounds is an extremely useful reaction in synthetic chemistry. Herein, we report the first diboration of a nitrile by an electron-rich diborane, mediated by an electrophilic borane. The reaction is metal-free, and all of the reagents are readily available.
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
19 July 2017
|
| In: |
Angewandte Chemie. International edition
Year: 2017, Jahrgang: 56, Heft: 38, Pages: 11645-11648 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201706001 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/anie.201706001 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201706001 
|
| Verfasserangaben: | Markus Frick, Elisabeth Kaifer, and Hans-Jörg Himmel |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1574264990 | ||
| 003 | DE-627 | ||
| 005 | 20230427042853.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180508s2017 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/anie.201706001 |2 doi | |
| 035 | |a (DE-627)1574264990 | ||
| 035 | |a (DE-576)504264990 | ||
| 035 | |a (DE-599)BSZ504264990 | ||
| 035 | |a (OCoLC)1341009402 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 33 |2 sdnb | ||
| 100 | 1 | |a Frick, Markus |e VerfasserIn |0 (DE-588)1158634072 |0 (DE-627)1020621591 |0 (DE-576)504265660 |4 aut | |
| 245 | 1 | 0 | |a Metal-free nitrile diboration through activation by an electron-rich diborane |c Markus Frick, Elisabeth Kaifer, and Hans-Jörg Himmel |
| 264 | 1 | |c 19 July 2017 | |
| 300 | |a 4 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 08.05.2018 | ||
| 520 | |a Diboration of unsaturated organic compounds is an extremely useful reaction in synthetic chemistry. Herein, we report the first diboration of a nitrile by an electron-rich diborane, mediated by an electrophilic borane. The reaction is metal-free, and all of the reagents are readily available. | ||
| 650 | 4 | |a boron | |
| 650 | 4 | |a diboranes | |
| 650 | 4 | |a diboration | |
| 650 | 4 | |a metal-free reactions | |
| 650 | 4 | |a nitriles | |
| 700 | 1 | |a Kaifer, Elisabeth |e VerfasserIn |0 (DE-588)1020547898 |0 (DE-627)691256624 |0 (DE-576)166913820 |4 aut | |
| 700 | 1 | |a Himmel, Hans-Jörg |d 1970- |e VerfasserIn |0 (DE-588)120090368 |0 (DE-627)080439683 |0 (DE-576)292036159 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Angewandte Chemie. International edition |d Weinheim : Wiley-VCH, 1998 |g 56(2017), 38, Seite 11645-11648 |h Online-Ressource |w (DE-627)320497879 |w (DE-600)2011836-3 |w (DE-576)111552060 |x 1521-3773 |7 nnas |a Metal-free nitrile diboration through activation by an electron-rich diborane |
| 773 | 1 | 8 | |g volume:56 |g year:2017 |g number:38 |g pages:11645-11648 |g extent:4 |a Metal-free nitrile diboration through activation by an electron-rich diborane |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1002/anie.201706001 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201706001 |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20180508 | ||
| 993 | |a Article | ||
| 994 | |a 2017 | ||
| 998 | |g 120090368 |a Himmel, Hans-Jörg |m 120090368:Himmel, Hans-Jörg |d 120000 |d 120200 |e 120000PH120090368 |e 120200PH120090368 |k 0/120000/ |k 1/120000/120200/ |p 3 |y j | ||
| 998 | |g 1020547898 |a Kaifer, Elisabeth |m 1020547898:Kaifer, Elisabeth |d 120000 |d 120200 |e 120000PK1020547898 |e 120200PK1020547898 |k 0/120000/ |k 1/120000/120200/ |p 2 | ||
| 998 | |g 1158634072 |a Frick, Markus |m 1158634072:Frick, Markus |d 120000 |d 120200 |e 120000PF1158634072 |e 120200PF1158634072 |k 0/120000/ |k 1/120000/120200/ |p 1 |x j | ||
| 999 | |a KXP-PPN1574264990 |e 3008524656 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"id":{"eki":["1574264990"],"doi":["10.1002/anie.201706001"]},"type":{"media":"Online-Ressource","bibl":"article-journal"},"physDesc":[{"extent":"4 S."}],"note":["Gesehen am 08.05.2018"],"relHost":[{"type":{"bibl":"periodical","media":"Online-Ressource"},"pubHistory":["37.1998 -"],"recId":"320497879","disp":"Metal-free nitrile diboration through activation by an electron-rich diboraneAngewandte Chemie. International edition","titleAlt":[{"title":"Angewandte Chemie / International edition"}],"language":["eng"],"part":{"volume":"56","text":"56(2017), 38, Seite 11645-11648","year":"2017","pages":"11645-11648","extent":"4","issue":"38"},"id":{"issn":["1521-3773"],"doi":["10.1002/(ISSN)1521-3773"],"zdb":["2011836-3"],"eki":["320497879"]},"physDesc":[{"extent":"Online-Ressource"}],"note":["Gesehen am 20.12.2022","Fortsetzung der Druck-Ausgabe"],"corporate":[{"role":"isb","display":"Gesellschaft Deutscher Chemiker"}],"origin":[{"publisher":"Wiley-VCH","dateIssuedDisp":"1998-","dateIssuedKey":"1998","publisherPlace":"Weinheim"}],"title":[{"title":"Angewandte Chemie","subtitle":"a journal of the Gesellschaft Deutscher Chemiker","partname":"International edition","title_sort":"Angewandte Chemie"}]}],"origin":[{"dateIssuedKey":"2017","dateIssuedDisp":"19 July 2017"}],"name":{"displayForm":["Markus Frick, Elisabeth Kaifer, and Hans-Jörg Himmel"]},"recId":"1574264990","person":[{"display":"Frick, Markus","given":"Markus","family":"Frick","role":"aut"},{"role":"aut","display":"Kaifer, Elisabeth","given":"Elisabeth","family":"Kaifer"},{"family":"Himmel","display":"Himmel, Hans-Jörg","given":"Hans-Jörg","role":"aut"}],"title":[{"title_sort":"Metal-free nitrile diboration through activation by an electron-rich diborane","title":"Metal-free nitrile diboration through activation by an electron-rich diborane"}],"language":["eng"]} | ||
| SRT | |a FRICKMARKUMETALFREEN1920 | ||