Regular high-nuclearity species from square building blocks: a triangular 3 × [2 × 2] Ni12 complex generated by the self-assembly of three [2 × 2] Ni4 golecular grids
A dodecanuclear 3 × [2 × 2] nickel(II) complex has been obtained via the self-association of three tetranuclear [2 × 2] molecular grids. X-ray diffraction shows a “propeller-like” structure of the [Ni4]3 scaffold with a central μ3-hydroxide. The dodecanuclear species remains stable in solution and c...
Gespeichert in:
| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
July 5, 2012
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| In: |
Inorganic chemistry
Year: 2012, Jahrgang: 51, Heft: 14, Pages: 7445-7447 |
| ISSN: | 1520-510X |
| DOI: | 10.1021/ic300902z |
| Online-Zugang: | Verlag, kostenfrei, Volltext: http://dx.doi.org/10.1021/ic300902z Verlag, kostenfrei, Volltext: https://doi.org/10.1021/ic300902z 
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| Verfasserangaben: | Yurii S. Moroz, Serhiy Demeshko, Matti Haukka, Andriy Mokhir, Utpal Mitra, Michael Stocker, Paul Müller, Franc Meyer, Igor O. Fritsky |
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| 245 | 1 | 0 | |a Regular high-nuclearity species from square building blocks |b a triangular 3 × [2 × 2] Ni12 complex generated by the self-assembly of three [2 × 2] Ni4 golecular grids |c Yurii S. Moroz, Serhiy Demeshko, Matti Haukka, Andriy Mokhir, Utpal Mitra, Michael Stocker, Paul Müller, Franc Meyer, Igor O. Fritsky |
| 246 | 3 | 3 | |a Regular high-nuclearity species from square building blocks$da triangular 3 × [2 × 2] Ni 12 complex generated by the self-assembly of three [2 × 2] Ni 4 molecular grids |
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| 520 | |a A dodecanuclear 3 × [2 × 2] nickel(II) complex has been obtained via the self-association of three tetranuclear [2 × 2] molecular grids. X-ray diffraction shows a “propeller-like” structure of the [Ni4]3 scaffold with a central μ3-hydroxide. The dodecanuclear species remains stable in solution and can be deposited without decomposition on highly ordered pyrolytic graphite surfaces. | ||
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