Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersions
Novel families of ultrahigh-molecular-weight polyethylene (UHMWPE) nanocomposites, containing uniformly dispersed, functionalized graphene (FG) nanosheets, were prepared by means of the polymerization filling technique (PFT). Unparalleled by any other carbon and boehmite nanocomposites, FG/UHMWPE ex...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
August 30, 2012
|
| In: |
Macromolecules
Year: 2012, Jahrgang: 45, Heft: 17, Pages: 6878-6887 |
| ISSN: | 1520-5835 |
| DOI: | 10.1021/ma301376q |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1021/ma301376q Verlag, Volltext: https://doi.org/10.1021/ma301376q 
|
| Verfasserangaben: | Markus Stürzel, Fabian Kempe, Yi Thomann, Stefan Mark, Markus Enders, and Rolf Mülhaupt |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1576249166 | ||
| 003 | DE-627 | ||
| 005 | 20220814160907.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180611s2012 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/ma301376q |2 doi | |
| 035 | |a (DE-627)1576249166 | ||
| 035 | |a (DE-576)506249166 | ||
| 035 | |a (DE-599)BSZ506249166 | ||
| 035 | |a (OCoLC)1341011274 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Stürzel, Markus Roland |e VerfasserIn |0 (DE-588)1072433141 |0 (DE-627)827655142 |0 (DE-576)433859296 |4 aut | |
| 245 | 1 | 0 | |a Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersions |c Markus Stürzel, Fabian Kempe, Yi Thomann, Stefan Mark, Markus Enders, and Rolf Mülhaupt |
| 264 | 1 | |c August 30, 2012 | |
| 300 | |a 10 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 11.06.2018 | ||
| 520 | |a Novel families of ultrahigh-molecular-weight polyethylene (UHMWPE) nanocomposites, containing uniformly dispersed, functionalized graphene (FG) nanosheets, were prepared by means of the polymerization filling technique (PFT). Unparalleled by any other carbon and boehmite nanocomposites, FG/UHMWPE exhibited an unusual simultaneous improvement in stiffness, elongation at break, and effective nucleation of polyethylene crystallization at only 1 wt % FG content. FG nanosheets are ultrathin—with a thickness of only one carbon atom and lateral dimensions of several micrometers. Owing to the presence of surface hydroxyl groups on the FG, single FG/methylaluminoxane (MAO) nanosheets can be effectively dispersed in n-heptane, thus enabling immobilization of an MAO-activated chromium (Cr1) single-site catalyst on FG. In contrast to nanometer-scale carbon black (CB), multiwall carbon nanotubes (CNT), graphite, and nanoboehmite, which failed to form stable dispersions, FG/MAO/Cr1 afforded the highest catalyst activities and excellent morphological control. In polymerization filling, the integration of a nanoparticle dispersion into the polymerization process eliminated the need for special safety and handling precautions typically required by conventional compounding of nanoparticles with ultralow bulk densities. | ||
| 700 | 1 | |a Enders, Markus |e VerfasserIn |0 (DE-588)1019871857 |0 (DE-627)691043280 |0 (DE-576)358992818 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Macromolecules |d Washington, DC : Soc., 1968 |g 45(2012), 17, Seite 6878-6887 |w (DE-627)302719199 |w (DE-600)1491942-4 |w (DE-576)090855191 |x 1520-5835 |7 nnas |a Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersions |
| 773 | 1 | 8 | |g volume:45 |g year:2012 |g number:17 |g pages:6878-6887 |g extent:10 |a Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersions |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1021/ma301376q |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://doi.org/10.1021/ma301376q |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20180611 | ||
| 993 | |a Article | ||
| 994 | |a 2012 | ||
| 998 | |g 1019871857 |a Enders, Markus |m 1019871857:Enders, Markus |d 120000 |d 120200 |e 120000PE1019871857 |e 120200PE1019871857 |k 0/120000/ |k 1/120000/120200/ |p 5 | ||
| 999 | |a KXP-PPN1576249166 |e 3012415297 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"id":{"doi":["10.1021/ma301376q"],"eki":["1576249166"]},"origin":[{"dateIssuedDisp":"August 30, 2012","dateIssuedKey":"2012"}],"name":{"displayForm":["Markus Stürzel, Fabian Kempe, Yi Thomann, Stefan Mark, Markus Enders, and Rolf Mülhaupt"]},"relHost":[{"origin":[{"dateIssuedKey":"1968","publisher":"Soc.","dateIssuedDisp":"1968-","publisherPlace":"Washington, DC"}],"id":{"zdb":["1491942-4"],"eki":["302719199"],"issn":["1520-5835"]},"name":{"displayForm":["American Chemical Society"]},"title":[{"title":"Macromolecules","subtitle":"web edition","title_sort":"Macromolecules"}],"pubHistory":["1.1968 -"],"part":{"volume":"45","text":"45(2012), 17, Seite 6878-6887","extent":"10","year":"2012","issue":"17","pages":"6878-6887"},"type":{"media":"Online-Ressource","bibl":"periodical"},"note":["Gesehen am 18.11.08"],"disp":"Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersionsMacromolecules","recId":"302719199","language":["eng"]}],"physDesc":[{"extent":"10 S."}],"title":[{"title":"Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersions","title_sort":"Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersions"}],"person":[{"display":"Stürzel, Markus Roland","roleDisplay":"VerfasserIn","role":"aut","family":"Stürzel","given":"Markus Roland"},{"given":"Markus","family":"Enders","role":"aut","roleDisplay":"VerfasserIn","display":"Enders, Markus"}],"recId":"1576249166","language":["eng"],"note":["Gesehen am 11.06.2018"],"type":{"media":"Online-Ressource","bibl":"article-journal"}} | ||
| SRT | |a STUERZELMANOVELGRAPH3020 | ||