Straightforward synthesis of dipyrido-annelated NHC-Palladium(II) complexes by oxidative addition: dedicated to Robert Weiss on the occasion of his 70th birthday
A straightforward synthesis method for mixed phosphane dipyrido-annelated N-heterocyclic carbene (dipiy) palladium(II) complexes is presented. The key step is the oxidative addition of 6-bromodipyridoimidazolium bromides that can be prepared easily from dipyridine in a two step reaction. This new pr...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
17 January 2012
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| In: |
European journal of inorganic chemistry
Year: 2012, Issue: 9, Pages: 1423-1429 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201100905 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/ejic.201100905 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201100905 
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| Author Notes: | Verena Gierz, Alexander Seyboldt, Cäcilia Maichle‐Mössmer, Roland Fröhlich, Frank Rominger, and Doris Kunz |
| Summary: | A straightforward synthesis method for mixed phosphane dipyrido-annelated N-heterocyclic carbene (dipiy) palladium(II) complexes is presented. The key step is the oxidative addition of 6-bromodipyridoimidazolium bromides that can be prepared easily from dipyridine in a two step reaction. This new procedure avoids any generation of the free carbene as well as any transmetallation step. |
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| Item Description: | Gesehen am 13.06.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201100905 |