Straightforward synthesis of dipyrido-annelated NHC-Palladium(II) complexes by oxidative addition: dedicated to Robert Weiss on the occasion of his 70th birthday
A straightforward synthesis method for mixed phosphane dipyrido-annelated N-heterocyclic carbene (dipiy) palladium(II) complexes is presented. The key step is the oxidative addition of 6-bromodipyridoimidazolium bromides that can be prepared easily from dipyridine in a two step reaction. This new pr...
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| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
17 January 2012
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| In: |
European journal of inorganic chemistry
Year: 2012, Heft: 9, Pages: 1423-1429 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201100905 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/ejic.201100905 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201100905 
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| Verfasserangaben: | Verena Gierz, Alexander Seyboldt, Cäcilia Maichle‐Mössmer, Roland Fröhlich, Frank Rominger, and Doris Kunz |
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| 520 | |a A straightforward synthesis method for mixed phosphane dipyrido-annelated N-heterocyclic carbene (dipiy) palladium(II) complexes is presented. The key step is the oxidative addition of 6-bromodipyridoimidazolium bromides that can be prepared easily from dipyridine in a two step reaction. This new procedure avoids any generation of the free carbene as well as any transmetallation step. | ||
| 650 | 4 | |a Carbene complexes | |
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| 650 | 4 | |a N ligands | |
| 650 | 4 | |a N-Heterocyclic carbene | |
| 650 | 4 | |a NHC complexes | |
| 650 | 4 | |a Oxidation | |
| 650 | 4 | |a Oxidative addition | |
| 650 | 4 | |a Palladium | |
| 650 | 4 | |a Phosphane ligands | |
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