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Synthesis and characterization of 11-vertex platinaborane compounds having nido-PtB10H12 and nido-Pt2B9H10 skeletons

The reaction of closo-[B10H10]2− with [PtCl2(PPh3)2] in MeOH at reflux affords the B-methoxy substituted 11-vertex nido-platinaborane compound [(PPh3)2PtB10H10-8-H0.5(OCH3)0.5-10-(OCH3)] (1) and the known species [(PPh3)2PtB10H11-8-(OCH3)] (2) and 1,6-(PPh3)2B10H8 (3). The same reaction under solvot...

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Bibliographic Details
Main Authors: Nie, Yong (Author) , Enders, Markus (Author) , Siebert, Walter (Author)
Format: Article (Journal)
Language:English
Published: 2012
In: Polyhedron
Year: 2012, Volume: 31, Issue: 1, Pages: 607-613
DOI:10.1016/j.poly.2011.10.019
Online Access:Verlag, Volltext: http://dx.doi.org/10.1016/j.poly.2011.10.019
Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0277538711006358
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Author Notes:Yong Nie, Jin-Ling Miao, Chun-Hua Hu, Hai-Yan Chen, Man Sing Cheung, Zhen-Yang Lin, Markus Enders, Walter Siebert

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520 |a The reaction of closo-[B10H10]2− with [PtCl2(PPh3)2] in MeOH at reflux affords the B-methoxy substituted 11-vertex nido-platinaborane compound [(PPh3)2PtB10H10-8-H0.5(OCH3)0.5-10-(OCH3)] (1) and the known species [(PPh3)2PtB10H11-8-(OCH3)] (2) and 1,6-(PPh3)2B10H8 (3). The same reaction under solvothermal condition gives the partially degraded diplatinaborane [(PPh3)2(μ-PPh2)Pt2B9H7-3,9,11-(OMe)3] (4) with a novel nido-Pt2B9H10 skeleton. The new metallaborane compounds have been characterized by spectroscopic methods and single-crystal X-ray analyses. In particular, computational/theoretical chemistry supports the ultimate structural confirmation of 4. The structures of these metallaboranes exhibit interesting intra- and/or intermolecular C-H⋯O hydrogen bonding interactions. 
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