Modification of pyridine-terminated aromatic self-assembled monolayers by electron irradiation
Using a series of model systems, we studied the effect of electron irradiation on pyridine-terminated aromatic thiolate self-assembled monolayers (SAMs) on Au(111). All these SAMs exhibited behavior similar to that of oligophenyl-based films, viz. a progressive and extensive cross-linking, preventin...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
April 24, 2017
|
| In: |
The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2017, Volume: 121, Issue: 18, Pages: 9982-9990 |
| ISSN: | 1932-7455 |
| DOI: | 10.1021/acs.jpcc.7b02153 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1021/acs.jpcc.7b02153 Verlag, Volltext: https://doi.org/10.1021/acs.jpcc.7b02153 
|
| Author Notes: | Can Yildirim, Eric Sauter, Andreas Terfort, and Michael Zharnikov |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1577200977 | ||
| 003 | DE-627 | ||
| 005 | 20220814182418.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180703s2017 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/acs.jpcc.7b02153 |2 doi | |
| 035 | |a (DE-627)1577200977 | ||
| 035 | |a (DE-576)507200977 | ||
| 035 | |a (DE-599)BSZ507200977 | ||
| 035 | |a (OCoLC)1341013209 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Yildirim, Can |e VerfasserIn |0 (DE-588)1128845016 |0 (DE-627)883605325 |0 (DE-576)486106365 |4 aut | |
| 245 | 1 | 0 | |a Modification of pyridine-terminated aromatic self-assembled monolayers by electron irradiation |c Can Yildirim, Eric Sauter, Andreas Terfort, and Michael Zharnikov |
| 264 | 1 | |c April 24, 2017 | |
| 300 | |a 9 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 03.07.2018 | ||
| 520 | |a Using a series of model systems, we studied the effect of electron irradiation on pyridine-terminated aromatic thiolate self-assembled monolayers (SAMs) on Au(111). All these SAMs exhibited behavior similar to that of oligophenyl-based films, viz. a progressive and extensive cross-linking, preventing release of individual molecules and their fragments and slowing down and hindering the damage of the SAM/substrate interface. The pyridine moieties participated in the formation of the cross-linking network, which was accompanied by their chemical modification and partial hydrogenation. As a consequence, the nitrogen content in the films did not change significantly upon irradiation (only ∼10% for the densely packed SAMs) and the modified pyridine moieties became reactive toward carboxylic acid anhydrides. The extent of irradiation-induced modification and damage was found to depend strongly on the structural quality and packing density of the monolayers. The results of the experiments suggest several potential applications of pyridine-terminated aromatic SAMs in context of their modification by electron irradiation, in the framework of conventional and chemical lithography as well as advanced nanofabrication. | ||
| 700 | 1 | |a Sauter, Eric |e VerfasserIn |0 (DE-588)1148321241 |0 (DE-627)100862537X |0 (DE-576)49628410X |4 aut | |
| 700 | 1 | |a Zharnikov, Michael |e VerfasserIn |0 (DE-588)1118537629 |0 (DE-627)872019810 |0 (DE-576)479525889 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t The journal of physical chemistry. C, Energy, materials, and catalysis |d Washington, DC : Soc., 2007 |g 121(2017), 18, Seite 9982-9990 |h Online-Ressource |w (DE-627)519508645 |w (DE-600)2256522-X |w (DE-576)259487104 |x 1932-7455 |7 nnas |a Modification of pyridine-terminated aromatic self-assembled monolayers by electron irradiation |
| 773 | 1 | 8 | |g volume:121 |g year:2017 |g number:18 |g pages:9982-9990 |g extent:9 |a Modification of pyridine-terminated aromatic self-assembled monolayers by electron irradiation |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1021/acs.jpcc.7b02153 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://doi.org/10.1021/acs.jpcc.7b02153 |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20180703 | ||
| 993 | |a Article | ||
| 994 | |a 2017 | ||
| 998 | |g 1118537629 |a Zharnikov, Michael |m 1118537629:Zharnikov, Michael |d 120000 |d 120300 |e 120000PZ1118537629 |e 120300PZ1118537629 |k 0/120000/ |k 1/120000/120300/ |p 4 |y j | ||
| 998 | |g 1148321241 |a Sauter, Eric |m 1148321241:Sauter, Eric |d 120000 |d 120300 |e 120000PS1148321241 |e 120300PS1148321241 |k 0/120000/ |k 1/120000/120300/ |p 2 | ||
| 998 | |g 1128845016 |a Yildirim, Can |m 1128845016:Yildirim, Can |d 120000 |d 120300 |e 120000PY1128845016 |e 120300PY1128845016 |k 0/120000/ |k 1/120000/120300/ |p 1 |x j | ||
| 999 | |a KXP-PPN1577200977 |e 3015799207 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"person":[{"role":"aut","given":"Can","family":"Yildirim","display":"Yildirim, Can"},{"role":"aut","given":"Eric","family":"Sauter","display":"Sauter, Eric"},{"display":"Zharnikov, Michael","role":"aut","given":"Michael","family":"Zharnikov"}],"title":[{"title":"Modification of pyridine-terminated aromatic self-assembled monolayers by electron irradiation","title_sort":"Modification of pyridine-terminated aromatic self-assembled monolayers by electron irradiation"}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"physDesc":[{"extent":"9 S."}],"language":["eng"],"id":{"eki":["1577200977"],"doi":["10.1021/acs.jpcc.7b02153"]},"origin":[{"dateIssuedKey":"2017","dateIssuedDisp":"April 24, 2017"}],"name":{"displayForm":["Can Yildirim, Eric Sauter, Andreas Terfort, and Michael Zharnikov"]},"recId":"1577200977","note":["Gesehen am 03.07.2018"],"relHost":[{"disp":"Modification of pyridine-terminated aromatic self-assembled monolayers by electron irradiationThe journal of physical chemistry. C, Energy, materials, and catalysis","recId":"519508645","name":{"displayForm":["publ. weekly by the American Chemical Society"]},"origin":[{"dateIssuedDisp":"2007-","dateIssuedKey":"2007","publisher":"Soc.","publisherPlace":"Washington, DC"}],"id":{"eki":["519508645"],"issn":["1932-7455"],"zdb":["2256522-X"]},"language":["eng"],"physDesc":[{"extent":"Online-Ressource"}],"type":{"media":"Online-Ressource","bibl":"periodical"},"corporate":[{"display":"American Chemical Society","role":"isb"}],"title":[{"partname":"Energy, materials, and catalysis","title":"The journal of physical chemistry","title_sort":"journal of physical chemistry"}],"part":{"issue":"18","year":"2017","extent":"9","text":"121(2017), 18, Seite 9982-9990","pages":"9982-9990","volume":"121"},"pubHistory":["111.2007 -"],"titleAlt":[{"title":"The journal of physical chemistry <Washington, DC> / C"},{"title":"Nanomaterials and interfaces"},{"title":"JPC C"},{"title":"JPCC"}],"note":["Gesehen am 13.03.2023"]}]} | ||
| SRT | |a YILDIRIMCAMODIFICATI2420 | ||