Effects of the stationary phase and the solvent on the stereodynamics of biphep ligands quantified by dynamic three-column HPLC*
Dynamics and kinetics in a single stroke: The stereodynamics of the tropos-chiral diphosphine biphep and its 3,3′-dialkoxy analogues were investigated by enantioselective dynamic HPLC (DHPLC) and a novel three-column approach, in with the dynamics and kinetics of the interconversion were examined in...
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| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
09 February 2012
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| In: |
Angewandte Chemie. International edition
Year: 2012, Jahrgang: 51, Heft: 12, Pages: 2985-2988 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201107907 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/anie.201107907 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201107907 
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| Verfasserangaben: | Frank Maier and Oliver Trapp |
| Zusammenfassung: | Dynamics and kinetics in a single stroke: The stereodynamics of the tropos-chiral diphosphine biphep and its 3,3′-dialkoxy analogues were investigated by enantioselective dynamic HPLC (DHPLC) and a novel three-column approach, in with the dynamics and kinetics of the interconversion were examined in a single experimental setup (see scheme). |
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| Beschreibung: | Gesehen am 15.08.2018 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201107907 |