Cyanide-bridged FeIII-CuII complexes: Jahn-Teller isomerism and its influence on the magnetic properties
We report here the synthesis and characterization of four dinuclear cyanide-bridged FeIII-CuII complexes, based on a tetra- or a pentadentate bispidine ligand (L1 or L2, respectively; bispidines are 3,7-diazabiyclo[3.3.1]nonane derivatives) coordinated to the CuII center, and a tridentate bipyridine...
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
August 20, 2012
|
| In: |
Inorganic chemistry
Year: 2012, Jahrgang: 51, Heft: 17, Pages: 9357-9368 |
| ISSN: | 1520-510X |
| DOI: | 10.1021/ic301122h |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1021/ic301122h Verlag, Volltext: https://doi.org/10.1021/ic301122h 
|
| Verfasserangaben: | Mihail Atanasov, Peter Comba, Stefan Helmle |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1580197876 | ||
| 003 | DE-627 | ||
| 005 | 20230427065649.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180820s2012 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/ic301122h |2 doi | |
| 035 | |a (DE-627)1580197876 | ||
| 035 | |a (DE-576)510197876 | ||
| 035 | |a (DE-599)BSZ510197876 | ||
| 035 | |a (OCoLC)1341016931 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Atanasov, Mihail |d 1953- |e VerfasserIn |0 (DE-588)1084217066 |0 (DE-627)848437578 |0 (DE-576)456226540 |4 aut | |
| 245 | 1 | 0 | |a Cyanide-bridged FeIII-CuII complexes |b Jahn-Teller isomerism and its influence on the magnetic properties |c Mihail Atanasov, Peter Comba, Stefan Helmle |
| 246 | 3 | 3 | |a Cyanide-bridged Fe III-Cu II complexes |
| 264 | 1 | |c August 20, 2012 | |
| 300 | |a 12 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 20.08.2018 | ||
| 500 | |a Im Titel ist "III" und "II" hochgestellt | ||
| 520 | |a We report here the synthesis and characterization of four dinuclear cyanide-bridged FeIII-CuII complexes, based on a tetra- or a pentadentate bispidine ligand (L1 or L2, respectively; bispidines are 3,7-diazabiyclo[3.3.1]nonane derivatives) coordinated to the CuII center, and a tridentate bipyridineamide (bpca) coordinated to the low-spin FeIII site, with cyanide groups completing the two coordination spheres, one of them bridging between the two metal ions. The four structurally characterized complexes [{Fe(bpca)(CN)3}{Cu(L1·H2O)}]BF4, [{Fe(bpca)(CN)3}{Cu(L2)}][Fe(bpca)(CN)3]·5H2O, [{Fe(bpca)(CN)3}{Cu(L2·MeOH)}]PF6·MeOH·H2O, and [{Fe(bpca)(CN)3}{Cu(L2)}]PF6·2H2O belong to different structural isomers. The most important differences are structurally and electronically enforced (direction of the pseudo-Jahn-Teller mode) strong or weak interactions of the copper(II) center with the cyanide bridge. The related strength of the magnetic coupling of the two centers is analyzed with a combination of experimental magnetic, electron paramagnetic resonance (EPR), electronic spectroscopic data together with a ligand-field theory- and density functional theory (DFT)-based analysis. | ||
| 700 | 1 | |a Comba, Peter |d 1953- |e VerfasserIn |0 (DE-588)122976843 |0 (DE-627)082271712 |0 (DE-576)160608988 |4 aut | |
| 700 | 1 | |a Helmle, Stefan |e VerfasserIn |0 (DE-588)143326465 |0 (DE-627)644736259 |0 (DE-576)336469020 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Inorganic chemistry |d Washington, DC : American Chemical Society, 1962 |g 51(2012), 17, Seite 9357-9368 |h Online-Ressource |w (DE-627)301510911 |w (DE-600)1484438-2 |w (DE-576)090854942 |x 1520-510X |7 nnas |a Cyanide-bridged FeIII-CuII complexes Jahn-Teller isomerism and its influence on the magnetic properties |
| 773 | 1 | 8 | |g volume:51 |g year:2012 |g number:17 |g pages:9357-9368 |g extent:12 |a Cyanide-bridged FeIII-CuII complexes Jahn-Teller isomerism and its influence on the magnetic properties |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1021/ic301122h |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://doi.org/10.1021/ic301122h |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20180820 | ||
| 993 | |a Article | ||
| 994 | |a 2012 | ||
| 998 | |g 143326465 |a Helmle, Stefan |m 143326465:Helmle, Stefan |d 120000 |d 120200 |e 120000PH143326465 |e 120200PH143326465 |k 0/120000/ |k 1/120000/120200/ |p 3 |y j | ||
| 998 | |g 122976843 |a Comba, Peter |m 122976843:Comba, Peter |d 120000 |d 120200 |e 120000PC122976843 |e 120200PC122976843 |k 0/120000/ |k 1/120000/120200/ |p 2 | ||
| 999 | |a KXP-PPN1580197876 |e 3022621108 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"physDesc":[{"extent":"12 S."}],"relHost":[{"type":{"bibl":"periodical","media":"Online-Ressource"},"disp":"Cyanide-bridged FeIII-CuII complexes Jahn-Teller isomerism and its influence on the magnetic propertiesInorganic chemistry","note":["Gesehen am 22.03.23"],"corporate":[{"roleDisplay":"Herausgebendes Organ","display":"American Chemical Society","role":"isb"}],"language":["eng"],"recId":"301510911","pubHistory":["1.1962 -"],"part":{"text":"51(2012), 17, Seite 9357-9368","volume":"51","extent":"12","year":"2012","issue":"17","pages":"9357-9368"},"title":[{"title_sort":"Inorganic chemistry","title":"Inorganic chemistry"}],"physDesc":[{"extent":"Online-Ressource"}],"name":{"displayForm":["American Chemical Society"]},"origin":[{"publisherPlace":"Washington, DC","publisher":"American Chemical Society","dateIssuedKey":"1962","dateIssuedDisp":"1962-"}],"id":{"issn":["1520-510X"],"zdb":["1484438-2"],"eki":["301510911"]}}],"name":{"displayForm":["Mihail Atanasov, Peter Comba, Stefan Helmle"]},"origin":[{"dateIssuedKey":"2012","dateIssuedDisp":"August 20, 2012"}],"id":{"doi":["10.1021/ic301122h"],"eki":["1580197876"]},"type":{"bibl":"article-journal","media":"Online-Ressource"},"note":["Gesehen am 20.08.2018","Im Titel ist \"III\" und \"II\" hochgestellt"],"language":["eng"],"recId":"1580197876","titleAlt":[{"title":"Cyanide-bridged Fe III-Cu II complexes"}],"person":[{"given":"Mihail","family":"Atanasov","role":"aut","display":"Atanasov, Mihail","roleDisplay":"VerfasserIn"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Comba, Peter","given":"Peter","family":"Comba"},{"family":"Helmle","given":"Stefan","roleDisplay":"VerfasserIn","display":"Helmle, Stefan","role":"aut"}],"title":[{"title_sort":"Cyanide-bridged FeIII-CuII complexes","subtitle":"Jahn-Teller isomerism and its influence on the magnetic properties","title":"Cyanide-bridged FeIII-CuII complexes"}]} | ||
| SRT | |a ATANASOVMICYANIDEBRI2020 | ||