A palladium-catalyzed one-pot procedure for the regioselective dimerization and cyanation of indoles

A one-pot method for the regioselective dimerization and cyanation of indoles has been developed. The reaction uses safe and nontoxic K4[Fe(CN)6]·3H2O as the cyanating agent which introduces selectively a cyano group into the 3-position of biindoles with high efficiency.

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Bibliographische Detailangaben
Hauptverfasser: Kianmehr, Ebrahim (VerfasserIn) , Ghanbari, Mohammad (VerfasserIn) , Rominger, Frank (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 6 February 2012
In: Tetrahedron letters
Year: 2012, Jahrgang: 53, Heft: 15, Pages: 1900-1904
ISSN:1873-3581
DOI:10.1016/j.tetlet.2012.01.129
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1016/j.tetlet.2012.01.129
Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0040403912001864
Volltext
Verfasserangaben:Ebrahim Kianmehr, Mohammad Ghanbari, Nasser Faghih, Frank Rominger
Beschreibung
Zusammenfassung:A one-pot method for the regioselective dimerization and cyanation of indoles has been developed. The reaction uses safe and nontoxic K4[Fe(CN)6]·3H2O as the cyanating agent which introduces selectively a cyano group into the 3-position of biindoles with high efficiency.
Beschreibung:Gesehen am 22.08.2018
Beschreibung:Online Resource
ISSN:1873-3581
DOI:10.1016/j.tetlet.2012.01.129